Exam 2 - Gas laws Flashcards

1
Q

What is the Kinetic Theory of Matter?

A

It predicts how matter behaves based on certain assumptions and approximations, explaining differences between solids, liquids, and gases.

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2
Q

What are the three states of matter and their particle behavior?

A

Solids have tightly bound particles (vibrate), liquids have free space to move but particles are still attracted, and gases have particles that are far apart and move freely.

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3
Q

What causes phase changes in matter?

A

Increases in kinetic energy, typically in the form of heat.

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4
Q

What are the common physical properties of gases?

A

Gases expand to fill their containers, are highly compressible, have low densities, and form homogeneous mixtures.

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5
Q

How do gas molecules behave in terms of movement and interaction?

A

Gas molecules move independently with no forces keeping them together or pushing them apart.

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6
Q

What are the main points of the Kinetic Theory of Gases?

A

Gases consist of molecules in continuous random motion, the volume of molecules is negligible, and attractive/repulsive forces are weak.

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7
Q

How does temperature affect the kinetic energy of gas molecules?

A

The average kinetic energy of gas molecules depends only on the temperature, and energy is transferred during collisions but the average does not change if temperature is constant.

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8
Q

What are the different types of molecular speed in gases?

A

Most probable speed (ump), average speed (uav), and root mean squared speed (urms).

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9
Q

How does molar mass affect the speed of gas molecules?

A

At a given temperature, gases with lower molar masses have higher speeds.

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10
Q

What are the four properties that define the state of a gas sample?

A

Temperature (K), Pressure (atm), Volume (L), and Amount of gas (mol).

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11
Q

What is pressure in terms of gases?

A

Pressure is the amount of force applied to an area.

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12
Q

What does Boyle’s Law state?

A

The pressure of a gas is inversely related to its volume when temperature is constant. P1V1 = P2V2

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12
Q

How is atmospheric pressure defined?

A

It is the weight of air per unit of area.

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13
Q

What are the major gas laws?

A

Boyle’s Law, Charles’s Law, Gay-Lussac’s Law, Avogadro’s Law, Ideal Gas Law, Dalton’s Law, Graham’s Law, Henry’s Law, and the van der Waals Equation.

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14
Q

What is the Combined Gas Law?

A

It combines Boyle’s, Charles’s, and Gay-Lussac’s laws to relate pressure, volume, and temperature when the amount of gas is constant.

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14
Q

What does Charles’s Law state?

A

The temperature of a gas is directly related to its volume, with pressure and the amount of gas constant.

15
Q

What does Gay-Lussac’s Law state?

A

The pressure of a gas is directly related to its temperature, with volume and amount of gas constant.

16
Q

What does Avogadro’s Law state?

A

The volume of a gas is directly related to the number of moles of gas, with temperature and pressure constant. At STP, one mole of gas occupies 22.4 L.

17
Q

What is the Ideal Gas Law equation?

A

PV=nRT, where R = 0.08206L x atm x mol-1 x K-1

18
Q

What does Dalton’s Law state?

A

The total pressure of a gas mixture is the sum of the partial pressures of each gas. Each gas behaves as if it were alone in the container.

19
Q

What does Graham’s Law state?

A

The rate of effusion or diffusion of a gas is inversely proportional to the square root of its molar mass. Lighter gases move faster.

20
Q

What does Henry’s Law state?

A

The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas in equilibrium with the liquid.

21
Q

How do real gases differ from ideal gases?

A

Real gases deviate from ideal behavior at high pressure and low temperature due to intermolecular forces and the volume occupied by gas molecules.

22
Q

What is the van der Waals Equation?

A

It adjusts the Ideal Gas Law to account for molecular volume and intermolecular forces

23
Q

How does atmospheric pressure change with altitude?

A

As altitude increases, atmospheric pressure decreases.

24
Q

Pneumonic for gas laws

A

Boyles a Pervert = pressure/volume is inverse
Charles law - Charles likes tv: temp =volume
Gay lussac- physical therapy is gay: pressure = temp
Combined: those 3 combined - BCG
Avogadros law: rotten avocados take up space - volume = moles
Ideal gas law: BCA - Boyles Charles avogadro
Grahams law: decreased molecular mass = increased speed (smaller equals faster)
Henrys law: ???
Henry Dalton’s law: gasses dont mix, they act as separate gasses.
Van der waals: real gasses such as oxygen, break down at increased pressure and/or decreased temp