enthalpy Flashcards
what is the enthalpy change of a reaction?
the heat energy it releases or absorbs per mole
+ means what for the heat energy?
absorbed
- means what for the heat energy?
released
+ heat energy is known as what?
endothermic
- heat energy is known as what?
exothermic
does breaking bonds release or absorb energy?
absorbs energy
does making bonds release or absorb energy?
releases energy
what is calorimetry?
an experimental method used to measure an enthalpy change
calorimetry : what happens in an exothermic reaction?
- the reaction releases heat energy
- that heat energy is absorbed by nearby water
- the temperature of the water increases
what does the simplest form of calorimetry involve?
- combusting a fuel to heat up the water
method for combustion calorimetry? (4 steps)
1) weigh out 50g of water and place it in a can above the burner
2) measure the initial mass of the burner and the initial temperature of the water
3) ignite the burner, stir water for 30 seconds, then extinguish the burner
4) measure the final mass of the burner and the final temperature of the water
what are the 2 most significant causes of error in combustion calorimetry?
- heat loss - most of the heat energy dissipates into the air instead of the water
- incomplete combustion - this releases less heat energy than expected
what is the method used for solution calorimetry? ( 4 steps)
1) pipette 25cm3 of CuSO4 into a polystyrene cup
2) measure the initial temperature of the solution
3) add 1g of Mg and stir continuously
4) measure the maximum temperature of the solution
what are 3 significant causes of error in solution calorimetry?
- heat loss
- incomplete reaction
- the water wasnt pure water- it has things dissolved in it, that means the SHC of the water is not 4.18 anymore