alcohols Flashcards

1
Q

what are alcohols?

A

organic molecules containing an OH- functional group

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2
Q

what does the start of the name show?

A

the number of carbon atoms it has

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3
Q

what does the end of the name show?

A

-ol to show its an alcohol `

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4
Q

what are the 3 main categories of formula used to represent alcohols on paper?

A

molecular formula
structural formula
displayed formula

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5
Q

what does the molecular formula show?

A

just each element, only once
doesn’t show the structure of the molecule at all

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6
Q

what does the displayed formula show?

A

each atom and every bond drawn out
perfectly shows the structure of the molecule

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7
Q

what are the 2 methods to make ethanol?

A

hydration of ethene
fermentation of glucose

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8
Q

in hydration of ethene, what is ethene mixed with?

A

steam

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9
Q

what are the conditions for the hydration of ethene?

A

300 degrees celsius
65 atm pressure
phosphoric acid (H3PO4) catalyst

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10
Q

what raw material provides the ethene in the hydration of ethene?

A

crude oil

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11
Q

what are the advantages of the hydration of ethene?

A

makes pure ethanol
can run continously

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12
Q

what are the disadvantages of the hydration of ethene?

A

conditions require lots of energy
non- renewable raw material used

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13
Q

what happens in the fermentation of glucose?

A

glucose is fermented microbiologically under the following conditions:
yeast- provides enzymes
30 degrees celsius- enzymes optimum temperatures
anaerobic- prevents oxidation

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14
Q

what raw material in the fermentation of glucose provides the glucose?

A

sugar cane

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15
Q

what are the advantages of the fermentation of glucose?

A

renewable raw material used
conditions not energy intensive

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16
Q

what are the disadvantages of the fermentation of glucose?

A

makes impure ethanol
must be done in individual batches

17
Q

what are the 3 ways ethanol can be oxidised?

A

combustion
microbial oxidation
chemical oxidation

18
Q

why does ethanol combust completely?

A

because of the oxygen atom in the OH- group

19
Q

what flame does the combustion of ethanol have?

A

a non-luminous, blue flame

20
Q

formula for combustion of ethanol?

A

C2H5OH + 3O2 -> 2CO2 + 2H2O

21
Q

what do micro-organisms use to oxidise ethanol into ethanoic acid?

A

the oxygen in the air

22
Q

under what conditions can microbial oxidation happen?

A

aerobically- if the microorganism is growing in the presence of air

23
Q

what does the (O) show?

A

the microbial use of oxygen in an equation

24
Q

what is the equation for microbial oxidation?

A

C2H5OH + 2(O) -> CH3COOH + H2O

25
Q

what do we use when we want to deliberately oxidise ethanol in the lab?

A

we heat it with a mixture of:
potassium dichromate (VI) (K2Cr2O7)
dilute sulphuric acid (H2SO4)

26
Q

what does chemical oxidation form?

A

ethanoic acid

27
Q

what is the formula for chemical oxidation?

A

C2H5OH + 2(O) -> CH3COOH + H2O

28
Q

what are the orange dichromate (VI) ions turned into?

A

green chromium (III) ions