Electronic Structure of the Atom Flashcards

1
Q

nodes

A

empty spaces between subshells

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2
Q

S subshell

A

in all 7 pel, 1 orbital, max 2 electrons

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3
Q

P subshell

A

2-7 pel, 3 orbitals, max 6 electrons

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4
Q

d subshell

A

3-7 pel, 5 orbitals, max 10 electrons

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5
Q

f subshell

A

3-5 pel, 7 orbitals, max 14 electrons

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6
Q

S subshell shape

A

shperical

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7
Q

p subshell shape

A

dumbbell

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8
Q

d subshell shape

A

dumbbell and spherical

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9
Q

f subshell

A

dumbbell and spherical

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10
Q

electron configurations

A

short hand configurations used to indicate the location of electrons in an atom

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11
Q

valence electrons

A

electrons found in the outer most principle energy level

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12
Q

orbital energy diagrams

A

indicate the location of electrons as well as the energy of the electron

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13
Q

hybridization

A

occurs when electrons shift to higher or lower orbitals

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14
Q

elements that hybridize naturally

A

carbon, silicon, chromium, molybdenum, tungsten?

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15
Q

Aufbau principle

A

electrons enter orbitals with the lowest energy first

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16
Q

Pauli Exclusion Principle

A

no two electrons in any atom may have the same set of quantum numbers; therefore electrons within the same orbitals must have opposite spins

17
Q

Hund’s Rule

A

within a subshell; one electron will enter each orbital with parallel spins before pairing will begin

18
Q

electronegativity

A

the ability of an atom in a chemical compound to attract electrons

19
Q

Why does the electronegativity of an atom increase as you go up and across on the periodic table?

A

because as the number of protons increase down the group, the attractions decreases with distance

20
Q

electron shielding

A

when the valence electrons never feel the full force of the protons (attractive forces)

21
Q

ionization energy

A

the energy required to remove a valence electron

22
Q

What is the relationship between the atomic radius and the periodic table?

A

It increases as you go down and across from right to left.

23
Q

light

A

electromagnetic waves, which travel through a vacuum at a rate of 3.0x10^10 cm/sec

24
Q

How do you calculate frequency?

A

Frequency = # of waves (cycles) / second

25
Q

speed of light (C)

A

3.0 x 10^10 cm / sec

26
Q

blue shift

A

towards

27
Q

red shift

A

away

28
Q

line (discontinuous) spectra

A

when an element in its gas state exposed to an electric charge and the light emitted is passed through a prism

29
Q

quantum numbers

A

used to indicate the location of electrons in an atom

30
Q

ground state

A

when electrons are in the lowest possible energy levels

31
Q

n

A

pel

32
Q

l

A

subshell

33
Q

m1

A

orbital

34
Q

ms

A

e spin

35
Q

John Dalton

A

defined the atom as an indestructible mass

36
Q

Joseph Thomson

A

discovered the negatively charged electron, developed “Plum Pudding” model

37
Q

Ernest Rutherford

A

discovered nucleus with protons and neutrons, couldn’t explain why electrons didn’t collapse (they were quantized)

38
Q

Schrodiner

A

Schrodinger equation: describes mathematically the location and energy of electrons in the hydrogen atom