Chemical Equilibrium Flashcards
chemical equilibrium
established when two opposite reactions occur at the SAME RATE, with no observable changes taking place
equilibrium is affected by…
temperature, pressure, and concentration
conditions required for equilibrium
- system is closed
- opposite reactions occur at the same RATE
- equilibrium is established by starting the reaction with either the reactants or the products
Le Chatelier’s Principle
if a system is in a state of equilibrium and i subjected to change or stress, the equilibrium will shift to counteract the imposed change, and a new state of equilibrium will be established
pressure effects on equilibrium
- ↑ pressure will shift equilibrium to the side with the fewest number of gas particles
- ↓ pressure will shift equilibrium to the side with the greatest number of gas particles
temperature effects on equilibrium
- ↑ temp. will favor the endothermic reaction
2. ↓ temp. will favor the exothermic reaction
concentration effects on equilibrium
- ↑ concentration of any reactant or product will shift the equilibrium to the opposite side
- ↓ in concentration of any reactant or product will shift the equilibrium to the same side
Haber Process
industrial synthesis of ammonia gas under optimal conditions
N2(g) + 3H2(g) → 2NH3(g) + 92.4KJ
high pressure, low temperature, remove ammonia gas after it is produced
equilibrium constant (Keq)
Keq = [products] / [reactants]; Keq > 1, the products are favored; Keq < 1, the reactants are favored
solubility product constant (Ksp)
used to determine the amount o solubility for any solid, must be dissociation equations
Ksp = [products] / [reactants]
equilibrium constants for acids and bases (Ka, Kb)
Ka and Kb = [products] / [reactants]; Ka > 1, strong acid; Kb > 1 strong base
amphiprotic
acts as both acid and base