Chemical Equilibrium Flashcards

1
Q

chemical equilibrium

A

established when two opposite reactions occur at the SAME RATE, with no observable changes taking place

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2
Q

equilibrium is affected by…

A

temperature, pressure, and concentration

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3
Q

conditions required for equilibrium

A
  1. system is closed
  2. opposite reactions occur at the same RATE
  3. equilibrium is established by starting the reaction with either the reactants or the products
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4
Q

Le Chatelier’s Principle

A

if a system is in a state of equilibrium and i subjected to change or stress, the equilibrium will shift to counteract the imposed change, and a new state of equilibrium will be established

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5
Q

pressure effects on equilibrium

A
  1. ↑ pressure will shift equilibrium to the side with the fewest number of gas particles
  2. ↓ pressure will shift equilibrium to the side with the greatest number of gas particles
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6
Q

temperature effects on equilibrium

A
  1. ↑ temp. will favor the endothermic reaction

2. ↓ temp. will favor the exothermic reaction

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7
Q

concentration effects on equilibrium

A
  1. ↑ concentration of any reactant or product will shift the equilibrium to the opposite side
  2. ↓ in concentration of any reactant or product will shift the equilibrium to the same side
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8
Q

Haber Process

A

industrial synthesis of ammonia gas under optimal conditions
N2(g) + 3H2(g) → 2NH3(g) + 92.4KJ
high pressure, low temperature, remove ammonia gas after it is produced

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9
Q

equilibrium constant (Keq)

A

Keq = [products] / [reactants]; Keq > 1, the products are favored; Keq < 1, the reactants are favored

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10
Q

solubility product constant (Ksp)

A

used to determine the amount o solubility for any solid, must be dissociation equations
Ksp = [products] / [reactants]

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11
Q

equilibrium constants for acids and bases (Ka, Kb)

A

Ka and Kb = [products] / [reactants]; Ka > 1, strong acid; Kb > 1 strong base

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12
Q

amphiprotic

A

acts as both acid and base

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