DN) enthalpy defintions Flashcards

1
Q

enthalpy of formation

A

enthalpy change when one mole of a substance is formed from its constituent elements with all substances in their standard states

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2
Q

enthalpy of combustion

A

enthalpy change when one mole of a substance undergoes complete combustion in oxygen with all substances in their standard states

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3
Q

enthalpy of neutralisation

A

enthalpy change when one mole of water is formed in a reaction between an acid and alkali under standard conditions

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4
Q

first ionisation energy

A

enthalpy change when each atom in one mole of gaseous atoms loses one electron to form one mole of gaseous 1+ ions

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5
Q

second ionisation energy

A

enthalpy change when each ion in one mole of gaseous atoms loses one electron to form one mole of gaseous 2+ ions

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6
Q

first electron affinity

A

enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous 1- atoms

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7
Q

second electron affinity

A

enthalpy change when each ion in one mole of gaseous 1- ions gains one electron to form one mole of gaseous 2- atoms

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8
Q

enthalpy of atomisation

A

enthalpy change when one mole of gaseous atoms is produced from an element in its standard state

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9
Q

hydration enthalpy

A

enthalpy change when one mole of gaseous ions become hydrated (dissolved in water)

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10
Q

enthalpy of solution

A

enthalpy change when one mole of an ionic solid dissolves in an amount of water large enough so that the dissolved ions are well separated and do not interact with each other

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11
Q

bond dissociation enthalpy

A

enthalpy change when one mole of covalent bonds is broken in the gaseous state

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12
Q

lattice enthalpy formation (or association)

A

enthalpy change when one mole of a solid ionic compound is formed from its constituent ions in the gas phase

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13
Q

lattice enthalpy of dissociation

A

enthalpy change when one mole of a solid ionic compound is broken up into its constituent ions in the gas phase

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14
Q

enthalpy of vaporization

A

enthalpy change when one mole of liquid is turned into a gas

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15
Q

enthalpy of fusion

A

enthalpy change when one mole of a solid is turned into a liquid

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16
Q

what is enthaply

A

energy change at a constant pressure

17
Q

enthalpy change

A

change in heat content at constant pressure

18
Q

circle with horizontal line through it = standard conditions

A

100kPa and 298k