DN) enthalpy defintions Flashcards
enthalpy of formation
enthalpy change when one mole of a substance is formed from its constituent elements with all substances in their standard states
enthalpy of combustion
enthalpy change when one mole of a substance undergoes complete combustion in oxygen with all substances in their standard states
enthalpy of neutralisation
enthalpy change when one mole of water is formed in a reaction between an acid and alkali under standard conditions
first ionisation energy
enthalpy change when each atom in one mole of gaseous atoms loses one electron to form one mole of gaseous 1+ ions
second ionisation energy
enthalpy change when each ion in one mole of gaseous atoms loses one electron to form one mole of gaseous 2+ ions
first electron affinity
enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous 1- atoms
second electron affinity
enthalpy change when each ion in one mole of gaseous 1- ions gains one electron to form one mole of gaseous 2- atoms
enthalpy of atomisation
enthalpy change when one mole of gaseous atoms is produced from an element in its standard state
hydration enthalpy
enthalpy change when one mole of gaseous ions become hydrated (dissolved in water)
enthalpy of solution
enthalpy change when one mole of an ionic solid dissolves in an amount of water large enough so that the dissolved ions are well separated and do not interact with each other
bond dissociation enthalpy
enthalpy change when one mole of covalent bonds is broken in the gaseous state
lattice enthalpy formation (or association)
enthalpy change when one mole of a solid ionic compound is formed from its constituent ions in the gas phase
lattice enthalpy of dissociation
enthalpy change when one mole of a solid ionic compound is broken up into its constituent ions in the gas phase
enthalpy of vaporization
enthalpy change when one mole of liquid is turned into a gas
enthalpy of fusion
enthalpy change when one mole of a solid is turned into a liquid