DN 4). Enthalpy Flashcards

1
Q

q=

A

mcΔT

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2
Q

q means and units

A

enthalpy change in Joules

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3
Q

m means and units

A

mass of substance in grams

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4
Q

c means and units

A

specific heat capacity Jg^(-1)K^(-1)

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5
Q

ΔT means and units

A

temperature change in ???? NOT SURE

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6
Q

specific heat capacity

A

the amount of heat needed to raise the temperature of 1g of substance by 1K

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7
Q

enthalpy change defintion

A

change in heat content at a constant pressure

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8
Q

enthalpy definition

A

heat content of a substance

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9
Q

Exothermic reaction

- A+B = C+D which has the greater enthalpy (A+B) or (C+D)

A

A+B

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10
Q

Exothermic reaction

- the enthalpy change is…..

A

negative

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11
Q

Exothermic reaction

- the temperature…..

A

increases

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12
Q

Exothermic reaction

- what happens during the reaction

A

heat is lost to the surroundings

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13
Q

Exothermic reaction

- what does the graph look like

A
reactants
                  |
                  |       ΔH = NEGATIVE
                  |
                  products
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14
Q

Exothermic reaction

- two examples

A

oxidation of fuels

respiration

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15
Q

Endothermic reaction

- A+B = C+D which has the greater enthalpy (A+B) or (C+D)

A

(C+D)

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16
Q

Endothermic reaction

- the enthalpy change is…

17
Q

Endothermic reaction

- the temperature….

18
Q

Endothermic reaction

- what happens during the reaction

A

heat is gained from the surroundings

19
Q

Endothermic reaction

- what does the graph look like

A
products      
                                |
                                |    ΔH = POSITIVE
                                |  
        reactants
20
Q

Endothermic reaction

- two examples

A

photosynthesis

thermal decomposition

21
Q

what does Ø mean (line through should be horizontal

A

standard conditions

22
Q

what are Ø (the standard conditions)

A

100KPa

298K or 25degrees c

23
Q

what does ΔHf^Ø mean

A

standard enthalpy of formation

24
Q

standard enthalpy of formation defintion

A

enthalpy change when 1 mole of substance is formed from it’s constituent elements under standard conditions and in their standard states

25
write ΔHf^Ø(H2O)
H2(g) + 1/2O2(g) --> H2O(l)
26
what does ΔHc^Ø mean
the standard enthalpy of combustion
27
standard enthalpy of combustion defintion
enthalpy change when 1 mole of substance is completely burned in oygen under standard conditions with all substances in standard state
28
write ΔHc^Ø(CH4)
CH4(g) + 2O2(g) --> CO2(g) + 2H2O(l)
29
enthalpy change (per mole) calculation
q / number of moles reacting
30
with extrapolating graphs, how to find ΔT
extrapolate top and bottom lines at the point where there is no measurement (cause this is where the reactants were added) find the vertical difference between the two lines
31
what does hess' law state
the enthalpy change for a reaction is dependent only on enthalpy of the reactants and prodicts and not the root taken
32
to use ΔHf^Ø values arrows go...
outwards
33
CRP (crap)
when using combustion values ΔH = sum of reactants - sum of products opposite = FPR
34
to use ΔHc^Ø values arrows go...
down / inwards