DN 4). Enthalpy Flashcards

1
Q

q=

A

mcΔT

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2
Q

q means and units

A

enthalpy change in Joules

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3
Q

m means and units

A

mass of substance in grams

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4
Q

c means and units

A

specific heat capacity Jg^(-1)K^(-1)

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5
Q

ΔT means and units

A

temperature change in ???? NOT SURE

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6
Q

specific heat capacity

A

the amount of heat needed to raise the temperature of 1g of substance by 1K

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7
Q

enthalpy change defintion

A

change in heat content at a constant pressure

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8
Q

enthalpy definition

A

heat content of a substance

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9
Q

Exothermic reaction

- A+B = C+D which has the greater enthalpy (A+B) or (C+D)

A

A+B

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10
Q

Exothermic reaction

- the enthalpy change is…..

A

negative

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11
Q

Exothermic reaction

- the temperature…..

A

increases

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12
Q

Exothermic reaction

- what happens during the reaction

A

heat is lost to the surroundings

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13
Q

Exothermic reaction

- what does the graph look like

A
reactants
                  |
                  |       ΔH = NEGATIVE
                  |
                  products
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14
Q

Exothermic reaction

- two examples

A

oxidation of fuels

respiration

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15
Q

Endothermic reaction

- A+B = C+D which has the greater enthalpy (A+B) or (C+D)

A

(C+D)

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16
Q

Endothermic reaction

- the enthalpy change is…

A

positive

17
Q

Endothermic reaction

- the temperature….

A

decreases

18
Q

Endothermic reaction

- what happens during the reaction

A

heat is gained from the surroundings

19
Q

Endothermic reaction

- what does the graph look like

A
products      
                                |
                                |    ΔH = POSITIVE
                                |  
        reactants
20
Q

Endothermic reaction

- two examples

A

photosynthesis

thermal decomposition

21
Q

what does Ø mean (line through should be horizontal

A

standard conditions

22
Q

what are Ø (the standard conditions)

A

100KPa

298K or 25degrees c

23
Q

what does ΔHf^Ø mean

A

standard enthalpy of formation

24
Q

standard enthalpy of formation defintion

A

enthalpy change when 1 mole of substance is formed from it’s constituent elements under standard conditions and in their standard states

25
Q

write ΔHf^Ø(H2O)

A

H2(g) + 1/2O2(g) –> H2O(l)

26
Q

what does ΔHc^Ø mean

A

the standard enthalpy of combustion

27
Q

standard enthalpy of combustion defintion

A

enthalpy change when 1 mole of substance is completely burned in oygen under standard conditions with all substances in standard state

28
Q

write ΔHc^Ø(CH4)

A

CH4(g) + 2O2(g) –> CO2(g) + 2H2O(l)

29
Q

enthalpy change (per mole) calculation

A

q / number of moles reacting

30
Q

with extrapolating graphs, how to find ΔT

A

extrapolate top and bottom lines
at the point where there is no measurement (cause this is where the reactants were added) find the vertical difference between the two lines

31
Q

what does hess’ law state

A

the enthalpy change for a reaction is dependent only on enthalpy of the reactants and prodicts and not the root taken

32
Q

to use ΔHf^Ø values arrows go…

A

outwards

33
Q

CRP (crap)

A

when using combustion values ΔH = sum of reactants - sum of products
opposite = FPR

34
Q

to use ΔHc^Ø values arrows go…

A

down / inwards