Cyanogenic and Isothiocyanate glycosides Flashcards

1
Q

Glycosides yielding hydrocyanic acid (HCN) as one of the products of hydrolysis

A

Cyanogenic glycoside

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2
Q

Both amygdalin and prunasin yield __ as __.

A

mandelonitrile, aglycones

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3
Q

Amygdalin is therefore a true glycoside rather than a maltoside True or False

A

True

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4
Q

Amygdalin (enzyme) (product)

A

amygdalin hydrolase, glucose + prunasin

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5
Q

Prunasin (enzyme) (product)

A

Prunasin hydrolase, glucose+ mandelonitrile

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6
Q

Mandelonitrile (enzyme) (product)

A

Mandelonitrile lyase, benzaldehyde + HCN

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7
Q

an enzyme obtained from almond kernels

A

Emulsin

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8
Q

Emulsin two enzymes

A

Amygdalase, prunase

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9
Q

Uses of emulsin

A
  1. Flavoring agent

2. Anti cancer (laetrile or Vit. B17) and possibility for control of sickle cell anemia

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10
Q

It is carefully dried stembark of Prunus serotina Ehrhart ( Fam. Rosaceae)

A

Wild cherry

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11
Q

Wild cherry is also known as

A

prunus virginia and wild black cherry tree

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12
Q

a compound formed by partial hydrolysis of

amygdalin

A

Prunasin

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13
Q

The yield of hydrocyanic acid varies from __ in the inner bark, __ in trunk bark, varies even in bark of the same thickness from the same tree

A

0.23%- 0. 32%, 0.03%

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14
Q

Wild cherry uses

A

Flavored vehicle especially in cough remedies

Sedative expectorant

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15
Q

Kernels of varieties of Prunus armeniaca Linne. ( Fam. Rosaceae)

A

Apricot pits

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16
Q

Does Prunus armeniaca Linne has a therapeutic effect?

A

None

17
Q

The seeds of several mustard family plants contain glycosides, the aglycones of which are isothiocyanates

A

Isothiocynate glycosides

18
Q

The glycosides are also termed

A

glucosinolates

19
Q

Mustard family (brassicaceae) which includes

A
  • Oilseeds (rapeseed)
  • Condiments (mustard and horseradish)
  • Vegetables (broccoli, cabbage, and turnips)
20
Q

–derived from indolylmethylglucosinolate

- shown to reduce risk of estradiol- linked mammary cancer

A

indole- 3-carbinol

21
Q
  • isolated from broccoli

- shown to induce anticarcinogenic protective enzymes

A

4- methylsulfinyl isothiocyanate

22
Q

from black mustard

A

Sinigrin

23
Q

from white mustard

A

Sinalbin

24
Q

from rapeseed

A

Gluconapin

25
Q

Black mustard also called

A

brown mustard, sinapis nigra

26
Q

Mustard is a dried ripe seeds of variety of

A

brassica nigra (linne.) Koch or of brassica juncea

27
Q

product in the hydrolysis of black mustard, it is volatile

A

Allyl isothiocyanate

28
Q

Allyl isothiocyanate commonly called

A

Volatile mustard oil

29
Q

Also called Sinapis Alba

A

White mustard

30
Q

Black mustard fixed oil

A

30-35%

31
Q

white mustard fixed oil

A

20- 25%