Chemical Tests Flashcards
Test for chloride + result.
- acidify with dilute nitric acid then add aqueous silver nitrate
- WHITE precipitate formed
Test for carbonate + result.
- add dilute acid
- effervescence and carbon dioxide gas produces
Test for bromide + result.
- acidify with dilute nitric acid then add aqueous silver nitrate
- CREAM precipitate formed
Test for iodide + result.
- acidify with dilute nitric acid then add aqueous silver nitrate
- YELLOW precipitate formed
Test for nitrate + result.
- add aqueous sodium hydroxide then aluminium foil, warm carefully
- ammonia produced
Test for sulfate + result.
- acidify with dilute nitric acid and then add aqueous barium nitrate/barium chloride
- white precipitate formed
acidifying with dilute nitric acid and then adding aqueous barium nitrate, white ppt formed
test for sulfate
reduction with aluminium foil and aqueous sodium hydroxide and then testing for ammonia gas
test for nitrate
acidifying with dilute nitric acid then adding aqueous silver nitrate
WHITE ppt: test for chloride
CREAM ppt: test for bromide
YELLOW ppt: test for iodide
reaction with dilute acid, effervescence and then testing for carbon dioxide gas
test for carbonate
Test for sulfite.
reaction with acidified aqueous potassium manganate (VII), which goes from purple to colourless
reaction with acidified aqueous potassium manganate (VII) which goes from purple to colourless
test for sulfite
How can we test for aqueous metal cations?
using aqueous sodium hydroxide and aqueous ammonia
We use aqueous sodium hydroxide and aqueous ammonia to test for…
aqueous metal cations
How can we test for aluminium cations (2 ways)?
- add aqueous NaOH, forms WHITE ppt. which is soluble in excess and gives a colourless solution
- add aqueous ammonia, forms WHITE ppt. which is insoluble in excess
How can we test for ammonium cations?
- add aqueous NaOH, produces ammonia gas on warming. it will turn red litmus blue
How can we test for calcium cations (2 ways)?
- add aqueous NaOH, white ppt. formed which is insoluble in excess
- add aqueous ammonia, forms no ppt. or very slightly white ppt.
How can we test for chromium (III) cations (2 ways)?
- add aqueous NaOH, green ppt. forms which is soluble excess
- add aqueous ammonia, green ppt. forms, which is insoluble in excess
How can we test for copper cations (2 ways)?
- add aqueous NaOH, light blue ppt. forms which is insoluble in excess
- add aqueous ammonia, light blue ppt. forms, which is soluble in excess and gives a dark blue solution
How can we test for iron (II) cations (2 ways)?
- add aqueous NaOH, green ppt. form which is insoluble in excess and turns brown near surface on standing
- add aqueous ammonia, same result
How can we test for iron (III) cations (2 ways)?
- add aqueous NaOH, red-brown ppt. forms which is insoluble in excess
- add aqueous ammonia, same result
How can we test for zinc cations (2 ways)?
- add aqueous NaOH, white ppt. forms which is soluble in excess and gives a colourless solution
- add aqueous ammonia, same result
After adding aqueous NaOH to Z, a soluble white ppt. forms which gives a colourless solution. What is Z?
zinc
After adding aqueous ammonia/NaOH to Z, an insoluble red-brown ppt. forms. What is Z?
iron (III) cations
After adding aqueous NaOH to Z, a soluble white ppt. forms which gives a colourless solution. What is Z?
aluminium cations
After adding aqueous ammonia to Z, a WHITE insoluble ppt. forms. What is Z?
aluminium cations
After adding aqueous ammonia to Z, ammonia gas is produced on warming. What is Z?
ammonium cations
After adding aqueous NaOH to Z, a white insoluble ppt. forms. What is Z?
calcium cations
After adding aqueous ammonia to Z, very slightly white ppt. forms. What is Z?
calcium cations
After adding aqueous NaOH to Z, a soluble green ppt. forms. What is Z?
chromium (III) cations
After adding aqueous ammonia to Z, an insoluble green ppt. forms. What is Z?
chromium (III) cations
After adding aqueous NaOH to Z, an insoluble light blue ppt. forms. What is Z?
copper cations
After adding aqueous ammonia to Z, a soluble light blue ppt. forms. which gives a dark blue solution. What is Z?
copper cations
After adding aqueous ammonia/NaOH to Z, an insoluble green ppt. forms. It turns brown near surface on standing. What is Z?
iron (II) cations
Test for ammonia gas.
damp red litmus paper turns blue
Test for carbon dioxide gas.
limewater turns milky
Test for chlorine gas.
damp litmus paper bleaches white
Test for hydrogen gas.
lit splint squeaky pop
Test for oxygen gas.
glowing splint relights
Test for sulfur dioxide gas.
turns acidified aqueous potassium manganate(VII) from purple to colourless
Flame colour for lithium, Li+.
red
Flame colour for sodium, Na+.
yellow
Flame colour for potassium, K+.
lilac
Flame colour for calcium, Ca2+.
orange-red
Flame colour for barium, Ba2+.
light green
Flame colour for copper, Cu2+.
blue-green
How should you carry out a flame test?
- nichrome wire with a loop at one end: clean loop in some HCl
- dip loop in substance to pick up a small volume
- place loop into hottest part of a Bunsen flame (tip of pale blue flame)
- observe colour
- clean the nichrome wire in HCl and repeat with other substances
acidifying with dilute nitric acid then adding aqueous silver nitrate
test for chloride/bromide/iodide
How can we test for aluminium cations (2 ways)?
- add aqueous NaOH, forms WHITE ppt. which is soluble in excess and gives a colourless solution
- add aqueous ammonia, forms WHITE ppt. which is insoluble in excess
How can we test for ammonium cations?
- add aqueous NaOH, produces ammonia gas on warming. it will turn red litmus blue
How can we test for calcium cations (2 ways)?
- add aqueous NaOH, white ppt. formed which is insoluble in excess
- add aqueous ammonia, forms no ppt. or very slightly white ppt.
How can we test for chromium (III) cations (2 ways)?
- add aqueous NaOH, green ppt. forms which is soluble excess
- add aqueous ammonia, green ppt. forms, which is insoluble in excess
How can we test for copper cations (2 ways)?
- add aqueous NaOH, light blue ppt. forms which is insoluble in excess
- add aqueous ammonia, light blue ppt. forms, which is soluble in excess and gives a dark blue solution
How can we test for iron (II) cations (2 ways)?
- add aqueous NaOH, green ppt. form which is insoluble in excess and turns brown near surface on standing
- add aqueous ammonia, same result