Chapter 9- Chemistry Flashcards
Solvation
The electrostatic interaction between solute and solvent molecules
An ideal solution
A solution with no enthalpy change in formation of the solution.
Solubility
The maximum amount of substance that can be dissolved in a particular solvent
Sparingly soluble salts
Solutes that dissolve with a molar solubility under 0.1 M
Two key solubility rules
All salts of group 1 metals are soluble
All nitrate salts are soluble (NO3)
Complex ions
A molecule in which a cat ion is bonded to at least one electron pair donor , called ligand
Chelation
Uses large organic ligands that can form multiple bonds with a central ion
Molarity versus molality
M =moles/Liters total solution
m = moles/Kg solvent
Normality (N)
The number of equivalence of interest per liter of solution
NaCl with m=12 =>N=24
Solubility product constant(Ksp)
Ksp= [Na][Cl]
Ion product
Analogous to the reaction quotient, the current concentrations of solute as applied to the solubility product constant.
Stability constant (Kf)
Used went to aqueous solutions are used to form the product in solution Kf=[product]/[aq][aq]
Common ion affect
Ions already in solution will prevent the dissolution of a solute
Raoults law
Vapor pressure is decreased with increased amount of solute in a solution
Pnew=X(mole fraction)Poriginal
Solution boiling point elevation
Change in temperature = i Kb m