Chapter 3- Bonds Flashcards
Chemical bonds
Formed by interaction of the valence electrons
Octet rule
Many exceptions, but rule of thumb it states that most atoms want 8 electrons in the outer most shell
Octet rule exceptions
Incomplete octet, elements that are stable with fewer than eight electrons.
Expanded octet, any element in period Three in greater has more than eight electrons in valence shell.
Odd numbers of electrons, cannot distribute to give 8 to each (NO)
Ionic bonding
Formation of an ion, electrons are transferred from a cation to an anion.
Covalent bonding
Electrons are shared between two Atoms
Bond length versus number of bonds
Decreased bond length = increased number of bonds.
Bond energy
The energy required to break a bond. More bonds equals more energy.
Polarity
Relative difference in electronegativities. Considered polar when the difference is between 0.5, and 1.7
Nonpolar 0-0.5
Coordinate covalent bonds
Both electrons originated from a single atom in a covalent bond
Formal charge equation
F= (typical valenc e-) - ( e- nonbonding) - (1/2 e- bonding)
Electronica geometry
Describes the arrangement of all pairs of electrons around the central atom
Molecular geometry
Describes the arrangement of only the bonding pairs of electrons.
Van set Walsall forces
Short-lived rapidly shifting dipoles that attract like materials. In all chemicals
Dipole dipole interactions
When the poles of polar covalent bonds attract or repulse each other
Hydrogen bonds
Only made with nitrogen, oxygen, or fluorine. Bonds form between the hydrogens and these atoms