Chapter 1 – atomic structure Flashcards

1
Q

Atomic number

A

Equal to the number of protons in an atom

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2
Q

Mass number

A

Equal to the total number of protons and neutrons in an atom

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3
Q

Isotope

A

Atoms with varying numbers of neutrons.

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4
Q

Valence electrons

A

Electrons on the outer most shell of an atom, and have the strongest interactions with the surrounding environment.

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5
Q

Cat ion

A

Cat = good, positively charged atom caused by the removal of an electron

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6
Q

An ion

A

A negatively charged atom Caused by an additional electron.

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7
Q

Hydrogen isotopes
Deuterium
Tritium
Protium

A
  • 1 proton, 1 neutron,
  • 1 proton, 2 neutrons
  • 1 proton, 0 neutrons
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8
Q

Atomic weight

A

The weighted average of different isotopes.

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9
Q

Max Planck’s energy equation

A

E=h(plancks constant) * f (frequency)

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10
Q

Planck’s constant

A

6.62610^-34js

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11
Q

Bohr’s electron angular momentum model

A

L= (ring #)(h)/(2pi)

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12
Q

Bohr’s energy equation

A

E=-(RH)/(n^2)

RH(rydberg’s constant)=2.18*10^-18

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13
Q

Ground state

A

State at which all electrons are in the lowest energy state

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14
Q

Excited state

A

When at least one electron has moved to a sub shell of a higher than normal energy

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15
Q

Energy equation based on photon emission

A

E=hc/wavelength

c is speed of light = 3*10^8

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16
Q

Lyman series

A

Electron drop from n>=2 to n=1

17
Q

Balmer series

A

Energy drop from n>=3 to n=2

18
Q

Paschen series

A

Energy drop Fromm>=4 to n=3

19
Q

Heisenberg uncertainty principle

A

Momentum and position of an electron cannot be simultaneously found.

20
Q

Quantum numbers and the pauli exclusion principle

A

Location of electrons can be given by their quantum number, and the exclusion principle states that new two electrons in a single atom can possess the same set of quantum numbers.

21
Q

Principal quantum number

A

n given by the Energy level at the electron is on.

22
Q

Azimuthal Quantum Number

A

( lower case L) can be any integer value les than or = to n-1

n=2 L=1 OR 0
n=1 L=0

23
Q

Spectroscopic notation

A
Notation of L quantum number
L=0=s
L=1=p
L=2=d
L=3=f
24
Q

Magnetic quantum number

A
Specifies the specific orbital that an electron is in given in values of negative L to positive L (-L,0,+L)
L=2(-2,-1,0,1,2)
P has 3 specific orbitals
D has 5 specific orbitals
Etc.
25
Q

Spin quantum number

A

+1/2 or -1/2

Spin of electron within orbital

26
Q

Paired electrons

A

Two electrons within the same orbital that have opposite quantum spin numbers(+,-)

27
Q

Parallel spin electrons

A

Electrons in different orbitals on the same energy level that have the same spin value(both + or both -)

28
Q

Equation for the maximum number of electrons within a sub shell

A

4L+2

29
Q

Equation for the maximum number of electrons within a shell

A

2n^2

30
Q

Electron configuration

A

Spectroscopic notation used to identify how electrons are configured within an atom.

31
Q

Aufbau principal

A

Electrons Phil lower the higher energy subshells 2S before 2P an 2P before 3s

32
Q

n+L rule

A

Lower n+L will be filled first
6s = 5+0
4d =4+2

33
Q

Anion electron configuration

A

Additional electrons are added to the configuration

2s2 2p5 -> 2s2 2p6

34
Q

Cat ion electron configuration

A

Electrons are removed from the highest value for n first, then highest L.

35
Q

Hund’s rule

A

Orbitals are filled so that there a maximum number of half filled orbitals with parallel spin

36
Q

Unpaired electrons cause materials to be paramagnetic

A

Materials will spin and orient in alignment with a magnetic field

37
Q

Materials with pair of electrons will be diamagnetic

A

Have a slight repulsion to a magnetic field