Chapter 2; The Chemistry Of Life Flashcards

1
Q

Biochemistry

A

study of the molecules that compose living organisms

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2
Q

Element

A

simplest form of matter to have unique chemical properties

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3
Q

Atomic Number

A

number of protons in the nucleus

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4
Q

Trace Elements

A

element that does not account for more than 0.02%

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5
Q

Minerals

A

inorganic elements extracted from the soil by plants and passed up the food chain to humans and other organisms

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6
Q

Atoms

A

particles so small that are not visible to the human eye

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7
Q

Protons

A

single positive charge

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8
Q

Neutrons

A

no charge

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9
Q

atomic mass

A

total number of protons and neutrons

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10
Q

Electrons

A

tiny particles with a single negative charge and very low mass

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11
Q

Electron levels

A

electrons swarm about the nucleus in concentric regions

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12
Q

valence electrons

A

electrons on the outermost shell that determine the chemical bonding properties of an atom

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13
Q

isotopes

A

each of two or more forms of the same element that contain equal numbers of protons but different numbers of neutrons in their nuclei

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14
Q

Deuterium

A

one proton and one neutron

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15
Q

Tritium

A

one proton and two neutrons

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16
Q

atomic weight (relative atomic mass)

A

mixture of isotopes

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17
Q

radioisotopes

A

unstable isotopes

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18
Q

radioactivity

A

process of decay

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19
Q

Ionizing radiation

A

destroys molecules and produces dangerous free radicals and ions in human tissues

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20
Q

mutagenetic

A

causing mutations in DNA

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21
Q

carcinogenic

A

triggering cancer as a result of mutation

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22
Q

alpha particles

A

consists of two protons and two neutrons

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23
Q

beta particle

A

free electron

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24
Q

gamma rays

A

very dangerous even when emitted by sources outside the body

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25
Q

physical half-life

A

the time required for 50% of its atoms to decay to a more stable state

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26
Q

biological half-life

A

time required for half of it to disappear from the body

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27
Q

ions

A

charged particles with unequal numbers of protons and electrons

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28
Q

background radiation

A

measure of the level of ionizing radiation present in the environment at a particular location

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29
Q

radon

A

a gas produced by the decay of uranium in the earth

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30
Q

anion

A

particle that gains electrons acquires a negative charge

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31
Q

cation

A

particle that loses electrons acquires a positive charge

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32
Q

Electrolytes

A

substances that ionize in water and form solutions capable of conducting electricity

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33
Q

Free radicals

A

chemical particles with an odd number of electrons

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34
Q

superoxide anion

A

when an additional electron is added, it becomes a free radical

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35
Q

antioxidant

A

a chemical that neutralizes free radicals

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36
Q

Superoxide dismutase (SOD)

A

enzyme that alternately catalyzes the dismutation of the superoxide radical into ordinary molecular oxygen and hydrogen peroxide

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37
Q

Molecules

A

chemical particles composed of two or more atoms united by a chemical bond

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38
Q

compounds

A

molecules composed of two or more elements

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39
Q

molecular formulae

A

represents molecules that identify their elements and show how many atoms of each are present

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40
Q

isomers

A

molecules with identical molecular formulae but different arrangements of their atoms

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41
Q

structural formulae

A

shows the location of each atom

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42
Q

molecular weight

A

sum of the atomic weights of its atoms

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43
Q

chemical bonds

A

a molecule that is held together and molecules are attached to one another by forces

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44
Q

ionic bond

A

relatively weak attraction between an anion and a cation

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45
Q

covalent bond

A

sharing of one or more pairs of electrons between nuclei

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46
Q

single covalent bond

A

sharing one electron pair

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47
Q

double covalent bond

A

sharing of two electron pairs

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48
Q

nonpolar covalent bond

A

covalent bond in which electrons are equally attracted to both nuclei

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49
Q

Polar covalent bond

A

covalent bond in which electrons are more attracted to one nucleus than to the other, resulting in slightly positive and negative regions in one molecule

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50
Q

Hydrogen bond

A

weak attraction between polarized molecules or between polarized regions of the same molecule

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51
Q

Van der Waals Force

A

weak, brief attraction due to random disturbances in the electron clouds of adjacent atoms (weakest bond)

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52
Q

mixture

A

consists of substances that are physically blended but not chemically combined

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53
Q

solvency

A

ability to dissolve other chemicals

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54
Q

universal solvent

A

water

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55
Q

hydrophilic

A

substances that dissolve in water

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56
Q

hydrophobic

A

substances that do not dissolve in water

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57
Q

hydration sphere

A

cluster of water molecules

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58
Q

adhesion

A

the tendency of one substance to cling to another

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59
Q

cohesion

A

tendency of molecules of the same substances to cling to each other

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60
Q

surface film

A

an elastic layer of water cohensed

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61
Q

chemical reactivity

A

ability to participate in chemical reactions

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62
Q

hydrolysis

A

ions that are incorporated into other molecules in the chemical reactions

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63
Q

thermal stability

A

helps to stabilize the internal temperature of the body

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64
Q

heat capacity

A

the amount of heat required to raise the temperature

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65
Q

calorie

A

base unit of heat

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66
Q

solution

A

mix of solutes and solvents

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67
Q

solute

A

particles of matter

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68
Q

solvent

A

more abundant substance

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69
Q

colloids

A

body are mixtures of protein and water

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70
Q

emulsion

A

a suspension of one liquid in another

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71
Q

acid (proton donor)

A

a molecule that releases a proton in water

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72
Q

base

A

proton accepter

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73
Q

pH

A

measure derived from the molarity of H+

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74
Q

neutral pH

A

7.0

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75
Q

acidic

A

pH below 7

76
Q

basic (alkaline)

A

pH above 7

77
Q

buffers

A

chemical solutions that resist changes in pH

78
Q

weight per volume

A

weight of solute in a given volume of solution

79
Q

percentage

A

weight of solute as a percentage of solution volume or volume of a liquid as a percentage of total solution volume

80
Q

molarity

A

measure of the number of moles of solute per liter of solution

81
Q

milliequivalents per liter

A

the unit of measure is used to express electrolyte to concentrations

82
Q

energy

A

capacity to do work

83
Q

work

A

to move something

84
Q

potential energy

A

energy contained in an object because of its position or internal state but that is not doing work at the time

85
Q

kinetic energy

A

energy of motion

86
Q

chemical energy

A

potential energy stored in the bonds of molecules

87
Q

heat

A

kinetic energy of molecular motion

88
Q

electromagnetic energy

A

kinetic energy of moving “packets” of radiation called photons

89
Q

electrical energy

A

both potential and kinetic energy

90
Q

free energy

A

potential energy available in a system to do useful work

91
Q

chemical reaction

A

process in which a covalent or ionic bond is formed or broken

92
Q

chemical equation

A

shows the reactants on the left, the products on the right, and an arrow pointing from the reactants to the products

93
Q

decomposition reactions

A

a large molecule breaks down into two or more smaller ones

94
Q

synthesis reactions

A

two or more small molecules combine to form a larger one

95
Q

exchange reactions

A

two molecules exchange atoms or groups of atoms

96
Q

reversible reactions

A

can go in either direction under different circumstances

97
Q

law of mass action

A

they proceed from the reactants in greater quantity to the substances with the lesser quantity

98
Q

equilibrium

A

the ratio of products to reactants is stable

99
Q

concentration

A

reaction rate increases when the reactants are more concentrated

100
Q

temperature

A

reaction rate increases as the temperature rises

101
Q

catalysts

A

substances that temporarily bind to reactants, hold them in a favorable position to react with each other, and may change the shapes of reactants in ways that make them more likely to react

102
Q

metabolism

A

all the chemical reactions in the body

103
Q

catabolism

A

consists of energy-releasing decomposition reactions

104
Q

exergonic reactions

A

energy-releasing reactions

105
Q

Anabolism

A

consists of energy-storing synthesis reactions

106
Q

endergonic reactions

A

reactions that require an Energy input

107
Q

oxidixing agent (electron acceptor)

A

molecule that takes the electrons

108
Q

reduction

A

a chemical reaction in which a molecule gains electrons and energy

109
Q

reducing agent (electron donor)

A

a molecule that donates electrons to another

110
Q

oxidation-reduction (redox) reactions

A

the oxidation of one molecule is always accompanied by the reduction of another

111
Q

organic chemistry

A

the study of compounds of carbon

112
Q

functional groups

A

small clusters of atoms that determine many of the properties of an organic molecule

113
Q

macromolecules

A

gigantic organic molecules

114
Q

polymerization

A

the joining of monomers to form a polymer

115
Q

dehydration synthesis (condensation)

A

living cells achieve this by means of a reaction

116
Q

dimer

A

the two monomers become joined by a covalent bond

117
Q

carbohydrate

A

a hydrophilic organic molecule with the general formula

118
Q

monosaccharides

A

the simplest carbohydrates

119
Q

glucose

A

the “blood sugar” that provides energy to most of our cells

120
Q

disaccharides

A

sugars composed of two monosacharides

121
Q

sucrose

A

glucose + fructose

122
Q

lactose

A

glucose + galactose

123
Q

maltose

A

glucose + glucose

124
Q

oligosaccharides

A

short chains of three or more monosaccharides

125
Q

polysaccharides

A

long chains

126
Q

glycogen

A

an energy-storage polysaccharide made by cells of the liver, muscles, brain, uterus, and vagina

127
Q

starch

A

corresponding energy-storage polysaccharide of plants

128
Q

cellulose

A

structural polysaccharide that gives strength to the cell walls of plants

129
Q

glycoproteins

A

major component of mucus

130
Q

proteoglycans

A

macromolecules in which the carbohydrate component is dominant and a peptide or protein forms a smaller component

131
Q

lipids

A

a hydrophobic organic molecule

132
Q

fatty acids

A

precursor of triglycerides, source of energy

133
Q

triglycerides (neutral fats)

A

energy storage; thermal insulation; filling space; binding organs together; cushioning organs

134
Q

phospholipids

A

major component of cell membranes; aid in fat digestion

135
Q

eicosanoids

A

chemical messengers between cells

136
Q

steroids

A

chemical messengers between cells

137
Q

bile acids

A

steroids that aid in fat digestion and nutrient absorption

138
Q

cholesterol

A

component of cell membranes; precursor of other steroids

139
Q

fat-soluble vitamins (ADEK)

A

involved in a variety of functions including blood clotting, wound healing, vision, and calcium absorption

140
Q

polyunsaturated fatty acids

A

those with multiple C=C bonds

141
Q

prostaglandins

A

five of the carbon atoms are arranged in a ring

142
Q

radical (R group)

A

the 20 amino acids used to make proteins are identical except for a third functional group

143
Q

peptide

A

any molecule composed of two or more amino acids joined by peptide bonds

144
Q

peptide bonds

A

formed by dehydration synthesis, joins the amino group of one amino acid to the carboxyl group of the next

145
Q

oligopeptides

A

chains of fewer than 10 or 15 amino acids

146
Q

polypeptides

A

chains larger than 15 amino acids

147
Q

conformation

A

three-dimensional shape

148
Q

primary structure

A

protein’s sequence of amino acids, which is encoded in the genes

149
Q

secondary structure

A

a coiled or folded shape held together by hydrogen bonds between the slightly negative -C=O group of one peptide bond and the slightly positive -NH group of another one some distance away

150
Q

alpha helix

A

springlike shape

151
Q

beta sheet

A

pleated, ribbonlike shape

152
Q

tertiary structure

A

formed by the further bending and folding of proteins into various globular and fibrous shapes

153
Q

alpha helix

A

spring-like shape

154
Q

globular proteins

A

a compact tertiary structure well suited for proteins embedded in cell membranes and proteins that must move around freely

155
Q

fibrous proteins

A

used for muscle contractions and providing strength to skin, hair, and tendons

156
Q

Quaternary Structure

A

the association of two or more polypeptide chains by noncovalent forces

157
Q

Denaturation

A

a more drastic conformational change in response to conditions

158
Q

conjugated proteins

A

non-amino acid moiety

159
Q

Keratin

A

a tough structural protein gives strength to nails, hair, and skin

160
Q

collagen

A

durable protein

161
Q

ligand

A

any hormone or molecule that reversibly binds to a protein

162
Q

molecular motors (motor proteins)

A

special power that some proteins can change shape repeatedly

163
Q

enzymes

A

proteins that function as biological catalysts

164
Q

substrate

A

enzyme’s action

165
Q

amylase

A

digests starch

166
Q

carbonic anhydrase

A

removes water

167
Q

activation energy

A

the energy needed to get the reaction started

168
Q

sucrase

A

an enzyme that breaks sucrose down to glucose and fructose

169
Q

active site

A

a substrate molecule approaches a pocket on the enzyme surface

170
Q

enzyme-substrate complex

A

the substrate binds to the enzyme

171
Q

enzyme-substrate specificity

A

the substrate slightly changes the shape of the enzyme to create a better fit between the two

172
Q

cofactor

A

about two-thirds of human enzymes require a nonprotein partner

173
Q

coenzymes

A

organic cofactors usually derived from niacin, riboflavin, and other water soluble vitamins

174
Q

aerobic respiration

A

uses energy from electrons to make ATP

175
Q

metabolic pathway

A

a chain of reactions with each step usually catalyzed by a different enzyme

176
Q

nucleotides

A

organic compounds with three principal components

177
Q

nitrogenous base

A

a single or double carbon-nitrogen ring

178
Q

adenine

A

double ring

179
Q

ribose

A

sugar

180
Q

adenosine triphosphate (ATP)

A

the body’s most important energy-transfer molecule

181
Q

adenosine triphosphatases (ATPases)

A

enzymes specialized to hydrolyze the third phosphate bond, producing ADP

182
Q

guanosine triphosphate (GTP)

A

another nucleotide involved in energy transfers

183
Q

cyclic adenosine monophosphate (cAMP)

A

a nucleotide formed by the removal of both the second and third phosphate groups from ATP

184
Q

nucleic acids

A

polymers of nucleotides

185
Q

deoxyribonucleic acid (DNA)

A

typically 100 million to 1 billion

186
Q

ribonucleic acid (RNA)

A

70-10,000 nucleotides long, carry out those instructions and synthesize the proteins, assembling amino acids in the right order to produce each protein “described” by the DNA