Ch 5 Flashcards

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1
Q

types of cellular work

A

synthetic, mechanical, concentration, electrical, heat generation, light generation

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2
Q

phototrophs

A

use light energy

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3
Q

chemotrophs

A

obtain energy through chemical bond oxidation

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4
Q

oxidation

A

removal of e- (releases energy)

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5
Q

reduction

A

addition of e- (requires energy input)

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6
Q

internal energy (E)

A

total energy stored within a system

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7
Q

delta E

A

E products - E reactants

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8
Q

H

A

change in enthalpy; heat content

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9
Q

exothermic

A

when delta H is negative (energy released)

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10
Q

endothermic

A

when delta H is positive (energy absorbed)

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11
Q

thermodynamic spontaneity

A

measure of whether or not a rxn or process can occur

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12
Q

directionality

A

rxns can only spontaneously proceed in one direction

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13
Q

free energy (G)

A

measure of spontaneity for a system alone

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14
Q

exergonic rxns

A

energy-yielding (spontaneous)

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15
Q

endergonic rxns

A

energy-requiring (not spontaneous)

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16
Q

equilibrium constant (Keq)

A

ratio of product concentration to reactant concentration at equilibrium

17
Q

delta G tells us…

A
  1. if a rxn is thermodynamically possible
  2. how much free energy would be liberated
18
Q

delta G does not tell us…

A

rxn rate or mechanism

19
Q

standard state

A

25 degrees C (298 K), 1 atm, product and reactant concentrations at 1M

20
Q

standard RT

A

592 cal/mol

21
Q

steady state

A

state of cellular activity maintained in order for cells to stay alive (cells in equilibrium are dead)