ch. 2 chem of life Flashcards

1
Q

chemical elements

element

A

simplest form of matter to have unique chemical properties

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2
Q

chemical elements

atomic number

A

number of protons in its nucleus

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3
Q

chemical elements

periodic table

A

elements arranged by atomic number

24 elements have biological rule

6 elements=98.5% of body weight (oxygen, carbon, hydrogen, nitrogen, calcium, and phosphorus)

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4
Q

chemical elements

minerals

A

inorganic elements extracted from soil by plants and passed up food chain to humans

Ca, P, Cl, Mg, K, Na, S

about 4% body weight

important for enzymes

electolytes: mineral salts needed for nerve and muscle function

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5
Q

atomic structure

nucleus

A

center of atom

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6
Q

atomic structure

proton

A

single + charge

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7
Q

atomic structure

neutron

A

no charge

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8
Q

atomic structure

atomic mass

A

equal to total number of protons and neutrons

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9
Q

atomic structure

electron

A

in concentric clouds surrounding nucleus

single - charge

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10
Q

atomic structure

an atom is electronically neutral as number of electrons equals number of

A

protons

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11
Q

atomic structure

valence electrons orbit in the

A

outermost shell and determine chemical bonding properties of an atom

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12
Q

isotopes and radioactivity

isotopes

A

varities of an element that differ only in the number of neutrons

extra neutrons increase atomic weight

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13
Q

isotopes and radioactivity

istoper of an element are chemically similar because they

A

have the same number of valence electrons

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14
Q

ions, electrolytes, free radicals

ion

A

charged particle with UNEQUAL number of protons and electron

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15
Q

ions, electrolytes, free radicals

ionization

A

transfer of electrons from one atom to another

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16
Q

ions, electrolytes, free radicals

anion

A

particle that GAINS electron

net negative

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17
Q

ions, electrolytes, free radicals

cation

A

particle that LOSES electron

net positive charge

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18
Q

ions, electrolytes, free radicals

ions with opposite charges are

A

attracted to each other

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19
Q

ions, electrolytes, free radicals

electrolytes

A

substances that ionize in water and form solutions capable of conducting electric current

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20
Q

ions, electrolytes, free radicals

Electrolyte importance

A

-Chemical reactivity, osmotic effects, electrical excitability
of nerve and muscle
– Electrolyte balance is one of the most important
considerations in patient care (imbalances can lead to
coma or cardiac arrest)

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21
Q

ions, electrolytes, free radicals

Free radicals

A
  • short-lived particles with an unusual
    number of electrons
    – Produced by normal metabolic reactions, radiation, certain
    chemicals
    – Trigger reactions that destroy molecules, and can cause
    cancer, death of heart tissue, and aging
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22
Q

Ions, Electrolytes, and Free Radicals

Antioxidants

A

– Chemicals that neutralize free radicals
– Superoxide dismutase (SOD) is an antioxidant enzyme in
the body
– Selenium, vitamin E, vitamin C, and carotenoids are
antioxidants obtained through the diet

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23
Q

Molecules and Chemical Bonds

Molecule

A

chemical particle composed of two or more atoms
united by a chemical bond

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24
Q

Molecules and Chemical Bonds

Compound

A

molecule composed of two or more different
elements

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25
# Molecules and Chemical Bonds Molecular formula
identifies constituent elements and how many atoms of each are present
26
# Molecules and Chemical Bonds Structural formula
identifies location of each atom
27
# Molecules and Chemical Bonds Isomers
- molecules with identical molecular formulae but different arrangement of their atoms
28
# Molecules and Chemical Bonds molecular weight (MW
of a compound is the sum of the atomic weights of its atoms
29
# Molecules and Chemical Bonds Chemical bonds
hold atoms together within a molecule or attract one molecule to another Most important types of chemical bonds: ionic bonds, covalent bonds, hydrogen bonds, van der Walls forces
30
# Molecules and Chemical Bonds Ionic bonds
* Attractions between anions and cations (example, NaCl) * Electrons donated from one atom to another * Easily broken by water
31
# Molecules and Chemical Bonds Nonpolar bond
electrons shared equally (strongest bond
32
# Molecules and Chemical Bonds Polar bond:
electrons shared unequally (spend more time near oxygen)
33
# Molecules and Chemical Bonds Hydrogen bond
a weak attraction between a slightly positive hydrogen atom in one molecule and a slightly negative oxygen or nitrogen atom in another – Water molecules are attracted to each other by hydrogen bonds – Large molecules (DNA and proteins) shaped by hydrogen bonds within them – Important to physiology
34
# Molecules and Chemical Bonds Van der Waals forces
weak, brief attractions between neutral atoms – Fluctuation in electron density within an atom creates polarity for a moment, and attracts adjacent atom for a very short time – Only 1% as strong as a covalent bond, but important in physiology (example, protein folding)
35
# Acids, Bases, and pH acid
proton donor releases ions in water
36
# acids bases and pH base
proton donor accepts ions
37
# acids bases pH pH
measure derived from the molarity of ph 7.0 neutral pH less than 7 is acidic more than 7 is basic
38
# acids bases pH pH is a measurement of molarity on a
logarithmic scale a change of one number on the pH scale represents a 10-fold change in concentration ph 4.0 is 10x more acidic than ph 5.0
39
# acids bases pH buffers
chemical solutions that resist changes in pH maintaining normal ph of blood is crucial for physiological functions
40
# metabolism oxidation reduction metabolism
all chemical reactions of the body
41
# metabolism oxidation reduction catabolism
energy-releasing decomposition reactions breaks covalent bonds produces smaller molecules
42
# metabolism oxidation reduction anabolism
energy-storing synthesis reactions requires energy input production of protein or fat
43
# metabolism oxidation reduction catabolism and anabolism are
inseparably linked anabolism is driven by energy released by catabolism
44
# metabolism oxidation reduction Oxidation
– A chemical reaction in which a molecule gives up electrons and releases energy – Molecule oxidized in this process – Electron acceptor molecule is the oxidizing agent * Oxygen is often involved as the electron acceptor
45
# metabolism oxidation reduction Reduction
– Any chemical reaction in which a molecule gains electrons and energy – Molecule is reduced when it accepts electrons – Molecule that donates electrons is the reducing agent
46
# Metabolism, Oxidation, and Reduction Oxidation-reduction (redox) reactions
– Oxidation of one molecule is always accompanied by reduction of another – Electrons are often transferred as hydrogen atoms
47
# carbon compunds and functional groups carbon has 4 valence
electrons binds with other atoms that can provide it with 4 more electrons to fill its valence shell
48
# carbon compunds and functional groups carbon atoms bind readily with
each other to form carbon backbones form long chains branched molecules and rings form covalent bonds with H, O, N, S carbon backbones carry a variety of functional groups
49
# carbohydrates hydrophilic organic molecule
ex sugars and starches "saccar-" and "-ose" both meaning sugar and sweet
50
# carbohydrates 3 important monosaccarides
glucose galactose fructose all isomers of each other produced by digestion of complex carbs
51
# carbohydrates 3 important disaccharides
sucrose-table sugar lactose-sugar in milk maltose-grain products
52
# carbohydrates 3 important ex of polysaccharides
glycogen- energy storage in cells of liver, muscle, brain, uterus, vagina starch- energy storage in plants that are DIGESTABLE cellulose- energy storage in plants that is important for human dietary fiber (INDIGESTABLE)
53
Carbs are a quickly mobilized source of energy
All digested carbs converted to glucose Oxidized to make ATP
54
Conjugated carb
Covalently bound to lipid or protein Ex glycolipids Glycoproteins Proteoglycans
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Glycolipids
External surface of cell membrane
56
Glycoproteins
External surface of cell membrane Mucus of respiratory and digestive tracts
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Proteoglycans
More carb than protein Gels that hold cells and tissues together Gelatinous filler in umbilical cord and eye Joint lubrication and cartilage texture
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Lipids are
Hydrophobic organic molecules with a high ratio of hydrogen to oxygen Have more calories per gram than carbs
59
5 primary lipids
Fatty acids Triglycerides Phospholipids Eicosanoids Steroids
60
Fatty acids
Chains of 4-24 carbon atoms with carboxyl group on one end and methyl group on the other –Saturated fatty acids have a lot of hydrogen –Unsaturated fatty acids contain some double bonds between carbons in chain (potential to add hydrogen) •Polyunsaturated fatty acids have multiple double bonds between carbons in chain –Essential fatty acids must be obtained from food
61
Triglycerides
Three fatty acids linked to glycerol –Each bond formed by dehydration synthesis –Broken down by hydrolysis
62
Triglycerides at room temperature
–When liquid, called oils •Often polyunsaturated fats from plants –When solid, called fat •Saturated fats from animals
63
Triglycerides primary function
energy storage –Also help with insulation and shock absorption (adipose tissue)