Ch 11 Organic Compound Summary Flashcards
Organic compounds are compounds that contain?
Carbon
Organic compounds consist of a ______ backbone and one or more ________ groups
carbon, functional
_______ functional groups consist of only carbon and hydrogen and include 1. _____, 2. _______, 3. _______ and 4.______
Hydrocarbon
alkanes, alkenes, alkynes, and aromatic compounds.
________ are hydrocarbons that contain all single bonds
Alkanes
Alkyl groups are ?
alkanes minus one hydrogen atom
What goes R represent?
A generic, nonspecific, alkyl group
alkene functional group is?
the carbon–carbon double bond
alkyne functional group is?
the carbon–carbon triple bond.
aromatic functional group (to a first approximation) is?
is a benzene ring
Alcohols and ethers are derived from?
Water
alcohol functional group is?
the hydroxyl (OH) group, so a generic alcohol may
be represented as R–OH.
ether functional group is?
an oxygen bonded to two alkyl groups. A generic
ether may be represented as R–O–R′.
functional group of an alkyl halide is?
a halogen atom (F,Cl,Br,or I)
Generically, halogens are represented as ?
X, so a generic alkyl halide may be represented as R–X.
Many inhaled anesthetics are ______ _______ that often contain _____ functional groups
Many inhaled anesthetic reagents are halogenated ethers that often contain ether functional groups.
What are three possible representations of Amines?
RNH2, R2NH, and R3N
Amines are derived from?
Ammonia, in which one of more hydrogens on ammonia have been replaced by an alkyl group.
carbonyl group is?
carbon doubly bonded to an oxygen
carbonyl-based functional groups include? (5)
aldehydes, ketones, carboxylic acids, esters, and amides
Aldehyde functional group has
a hydrogen atom bonded to a carbonyl group. A generic aldehyde may be represented as R(C = O)H.
Ketones functional group
have two alkyl groups bonded to a carbonyl group. A generic ketone may be represented as R2C = O.
Carboxylic acids have a
hydroxyl group bonded to a carbonyl group. A generic carboxylic acid may be represented as R(C = O)OH. Sometimes you’ll see this written as RCO2H or RCOOH.
Esters have
an alkoxy (OR) group bonded to a carbonyl group
condensation products between a carboxylic acid and an alcohol produce?
Ester and H2O
Amides have
a nitrogen atom bonded to a carbonyl group. generic amide may be represented as R(C = O)NR2. The R groups on nitrogen may be either alkyl groups or hydrogens.
Amides are condensation products between
carboxylic acid and an amines
Aldehydes and ketones undergo addition reactions with alcohols to form
hemiacetals or hemiketals
Functional group of a hemiacetal / hemiketal is characterized by
an ether functional group and an alcohol functional group on the same carbon.
In the presence of excess alcohol (and an acid catalyst), aldehydes and ketones condense with two alcohol molecules to form
acetals or ketals
The acetal/ketal functional group is characterized by
two ether functional groups on the same carbon.