Carbohydrates: monosaccharides & disaccharides Flashcards
Macromolecules
A macromolecule is a giant molecule made up of many repeating units (containing c). Such molecules are called as polymers & the individual units are called monomers.
Monomers
The monomers are covalently linked to make a polymer by removing water; chemical process called condensation.
Polymer
The polymers could be broken down by the addition of water; process called hydrolysis
Four major classes are:
Carbohydrates
Lipids
Protein
Nucleic acid
Monomers and their polymers
Monosaccharides to carbohydrates
Fatty acids & glycerol to lipids
Amino acids to proteins
Nucleotides to nucleic acid
Carbohydrates
They are compounds containing carbon, hydrogen & oxygen
The ratio of hydrogen to oxygen is usually 2:1
They have general formula (CH2O)n
Types of carbohydrates
Monosaccharides
Disaccharides
Polysaccharides
Carbohydrates: sugar
Monosaccharides and disaccharides
Monosaccharides (monomers) example
Glucose
Fructose
Ribose
Disaccharides (dimers) example
Sucrose
Maltose
Lactose
Polysaccharides (polymers) example
Starch
Cellulose
Glycogen
Types of carbohydrates: monosaccharides
Single, simple sugar
Types of carbohydrates: disaccharides
Consist of two monosaccharides joined by a condensation reaction ie glycosidic bond
Types of carbohydrates: polysaccharides
Polymers of many sugars joined by more than two condensation reactions ie glycosidic bonds
Monosaccharides
Simple sugar units which make up all other carbohydrates which cannot be further hydrolysed into smaller units
α-glucose: OH above or below
Hydroxyl (OH-) group of 1c projects below the plane of ring.
α-glucose
It is a primary substrate in cellular respiration & provides energy for most metabolic reactions
β- glucose: OH above or below
Hydroxyl (OH-) group of 1c projects upwards the plane of ring.
β- glucose
Is a component of the cellulose micro fibrils that are found in the cell wall of plants
Disaccharides
Two monosaccharides can be linked by glycosidic bonds to form disaccharides
2[(CH20)n]-H20
Condensation reaction: monosaccharides
During condensation reaction, 2 monosaccharides are joined by the removal of water molecules to form a covalent bond known as a glycosidic bond
Hydrolysis reaction
Hydrolysis is the splitting of a disaccharides into its monosaccharides by the addition of water molecules this process breaks glycosidic bonds
Condensation vs hydrolysis
Monosaccharides forms condensation reactions which forms disaccharides.
Disaccharides forms hydrolysis reactions which forms monosaccharides.
Condensation of monosaccharides
Glucose and glucose forms maltose and water
Glucose and fructose forms sucrose and water
Glucose and galactose forms lactose and water