Carbohydrates 2: polysaccharides Flashcards
Polysaccharides
Many monosaccharides can be linked by glycosidic bonds to form polysaccharides.
E.g glycogen, cellulose & starch
Polysaccharides are
Variable in length
Branched or unbranched
Straight or coiled
Folded ideal for energy storage
Polysaccharide Ideal for energy storage:
They can form very compact molecules which takes up less space.
They are physically and chemically inactive so they do not interfere which other cell functions of cell.
They are not very soluble so have almost no effect on water potential within cell & cause osmotic movements.
Starch
Starch is made up of many α glucose residues linked by glycosidic bonds.
Starch is a mixture of 2 compounds:
Amylose & amylopectin
Function of starch
Energy storage molecule in plant cells
Starch - structure related to function: compact
So more glucose can be stored in less space in a cell
Starch - structure related to function: insoluble
So cannot leave the cell easily & it does not have an osmotic effect
Starch - structure related to function: unreactive
So it does not get involved in chemical reactions of the cell
Starch - structure related to function: rapidly hydrolysed
Amylose and amylopectin can be rapidly hydrolysed by enzymes into maltose as they are highly branched
Glycogen
Made up of α glucose residues
Branches formed due to 1,6-glycosidic bonds
1,4 - glycosidic bonds are found in unbranched part
Branches formed due after 8 to 10 residues
Glycogen - structure related to function: compact
Glycogen is compact so it allows storage of large quantities of glucose in a small space
Glycogen - structure related to function: Insoluble
It is insoluble so it cannot leave the cell easily and does not have an osmotic effect
Glycogen - structure related to function: unreactive
It is relatively unreactive so it does not get involved in chemical reactions in cell
Glycogen - structure related to function: highly branched
It is highly branched so can be rapidly hydrolysed by enzymes into glucose and used for respiration in cells
Polysaccharides & energy: insoluble
They cannot leave the cell
Have no osmotic effect. So, cells can store lots of polysaccharides without the need for osmoregulation
Polysaccharides & energy: hydrolysed by enzymes
can be quickly hydrolysed by enzymes into glucose and used for respiration in cells
Polysaccharides & energy: relatively unreactive
They do not get involved in other metabolic reactions in cells
Polysaccharides & energy: compact
A lot of glucose is stored in small space within the cell
Source: cellulose
Plant
Source: starch (amylose)
Plant
Source: starch (amylopectin)
Plant
Source: glycogen
Animal
Subunits: cellulose
β-glucose
Subunits: starch (amylose)
α-glucose
Subunits: starch (amylopectin)
α-glucose
Subunits: glycogen
α-glucose
Bonds: cellulose
1,4
Bonds: starch (amylose)
1,4
Bonds: starch (amylopectin)
1,4 & 1,6
Bonds: glycogen
1,4 & 1,6
Branches: cellulose
No
Branches: starch (amylose)
No
Branches: starch (amylopectin)
Yes
(-per 20 subunits)
Branches: glycogen
Yes
(-per 10 subunits)