BIOL 111 Flashcards

1
Q

What do you call a monosaccharide with an aldehyde and what do you call one with a ketone

A

aldose and ketose

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2
Q

What do you call a monosaccharide with 3 carbons

A

triose

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3
Q

what side does the OH group sit on the D isomer

A

Right side

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4
Q

What is the relationship between number of chiral atoms and optical isomers

A

2^n

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5
Q

What does ketones and aldehydes reacting with hydroxyl groups mean for monosaccharides

A

It means they can form cyclic structures

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6
Q

Where is the anomeric caron for ketones and where is it for aldehydes

A

C-2 for ketones and C-1 for aldehydes

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7
Q

Name the two regions of a fatty acid

A

Carboxyl head group and hydrocarbon tail

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8
Q

what is the difference between the two regions of a fatty acid

A

Tail is hydrophobic and head is hydrophillic so they are amphipathic (two different chem characteristics)

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9
Q

What are the different suffixes for saturated, monounsaturated and polyunsaturated fatty acids

A

Saturated = anoic, monounsaturated = enoic
polyunsaturated = di/tri ect + enoic

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10
Q

what prefixes do you use for unsaturated fatty acid naming

A

cis and trans (can be multiple e.g cis,cis,trans-9,12,14-octadeca…)

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11
Q

Where do you start counting carbons on a fatty acid

A

at the carboxyl carbon

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12
Q

Why can’t animals synthesise fatty acids beyond carbon 9

A

They do not have the desaturase enzyme

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13
Q

what are essential fatty acids

A

unsaturated fatty acids that are needed but cannot be synthesised by animals

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14
Q

What are good sources of essential fatty acids

A

fish oils (eat microalgae) and plant based spreads (e.g flora)

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15
Q

What are the differences between neutral lipids and polar lipids

A

neutral lipids are energy stores whereas polar lipids have structural roles (e.g cell membranes)

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16
Q

What is the important feature of triglycerides

A

It is an efficient energy store (more so than carbohydrates)

17
Q

Why do polyunsaturated fats have lower melting points

A

They can’t pack as tightly together and have more fluidity

18
Q

What differences in structure do cis and trans fats have

A

trans double bonds do not cause a bend like cis so they do not effect melting point and are implicated in circulatory diseases (naturally occuring fats are usually cis)

19
Q

how are phosphoglycerides composed

A

Two fatty acids attatched to a glycerol and a phosphate attatched to the other side of the glycerol with a variable group on the phosphate

20
Q

Why are membranes important

A

1) Seperate cell contents from surroundings
2) Maintain different envirnoments inside and outside membrane (organelles)
3) Selectively permeable

21
Q

How do phopspholipids move in the membrane

A

They move laterally rapidly (roughly 2um/s) but very rarely flip-flop their orientation

22
Q

What affects membrane fluidity

A

1) cholesterol acts as temperature buffer
2) more unsaturated fatty acids prevent packing increasing membrane fluidity and vice versa

23
Q

What affects protein movement in natural membranes

A

The cells actin cytoskeleton essentially fences the proteins in limiting their movement unless they rarely “hop” into another area

24
Q

What function do glycoproteins and glycolipids have

A

They act as tags for cell regognition (recognised by receptor proteins)

25
Q

What are some functions of membrane proteins

A

1) Membrane bound enzymes
2) Signal transduction (receptors)
3) intercellular joining
4) attachment to the cytoskeleton and extracellular matrix to maintiain cell shape

26
Q

How long is an oligosaccharide usually

A

shorter chains, longer chains are polysaccharides

27
Q
A