Biodegradable Polymers Flashcards

1
Q

Biodegradable polymers

A

Can be made from finite resources such as crude oil but contain additives that cause it to degrade more quickly than traditional polymers

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2
Q

Natural bio-polymers

A

Polymers made from natural materials such as cellulose, starch and polysaccharides

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3
Q

Synthetic bio-polymers

A

Polymers made renewable resources but chemically engineered to break down more quickly

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4
Q

Implications of bio-polymers and biodegradable polymers

A

Can produce methane (greenhouse gas)when they decompose

Biodegradable polymers can take high temperatures to decompose and may leave behind toxic residues

Natural bio-polymers are made from crops and GM crops so require land

Can’t be recycled - discourages people to recycle and contributes to a throwaway culture

Can be processed the same way as thermoplastics - injection moulding, calendaring, vacuum formed and blow moulded

Can have additives added

Similar names of bio-polymers and biodegradable polymers may confuse people

Reduce the demand for oil based polymers

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5
Q

Corn starch polymer

A

Natural Bio-polymer

Made with high-starch vegetables such as corn, maize and potatoes

Uses:

Packaging 
Straws 
Vending cups 
Disposable cutlery 
Bags 
Takeaway food containers
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6
Q

Potatopak

A

Natural Bio-polymer

Made from potato starch

Cradle-to-cradle approach

Non-toxic, edible, biodegradable

Produces no toxic waste, but the small amounts of solid waste can be used to feed animals

Can be composted - will break down within 4 weeks

Uses:

Single use food items - bowls, cutlery, food trays, serviettes - can be easily formed into this shape using a heated compression mould

Packaging beads (aka peanuts)

Bin bags

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7
Q

Biopol (polyhydroxybutyrate (PHB))

A

Natural Bio-polymer

Made from bacteria grown in cultures - fermentation of carbohydrates from peas and sweet potatoes

Additive to promote degradation - usually 1% added to thermoplastic (BIO-BATCH ADDITIVE)

Can be composted

Uses:

Packaging film 
Carrier bags 
Vending cups 
Nappies 
Surgical stitches 
Pill coverings
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8
Q

Polylactic acid (PLA)

A

Synthetic bio-polymer

Made from corn kernels or can sugar, fermented to produce lactic acid and then synthesised to produce polylactic acid

Uses:

Single use bottles 
Carrier bags 
Plant pots 
Disposable nappies 
Medical sutures
3D printing
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9
Q

Polyhydroxyalkanoate (PHA)

A

Natural bio-polymer

Made from bacteria grown in cultures

Fully compostable

Uses:

Packaging
Medical uses - slow release medication patches, screws and bone plates

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10
Q

Lactide

A

Synthetic bio-polymer

Fully compostable, water soluble

PLA and cellulose based

Uses:

Biomedical applications
Slow-release medication
Bone repair fixings
Detergents washing sachets

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11
Q

Glycolide (Lactel and Ecofilm)

A

Synthetic bio-polymer

Fully compostable, water soluble

PLA and cellulose based

Uses:

Food film 
Bags 
Packaging wrap 
Bin bags 
Agricultural ground sheet 
Flower wrap
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12
Q

Photodegradable

A

Polymer bonds are weakened and the polymer breaks down with exposure to UV light such as sunlight

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13
Q

Oxy-degradable

A

Polymer turns into a fine powder with exposure to oxygen and is subsequently degraded by the action of microorganisms

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14
Q

Hydro-degradable

A

Polymer quickly breaks down with exposure to water and is subsequently degraded by the action of microorganisms

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15
Q

Degradation by microorganisms

A

Convert the material into water, carbon dioxide, biomass and methane

The ability of a polymer to biodegrade is dependent on the structure rather than the origin of e raw material

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16
Q

Biodegradable polymer examples

A

Corn starch polymer

Potatopak

Biopol (polyhydroxybutyrate (PHB))

Polyhydroxyalkanoate (PHA)

Lactide

Glycolide (Lactel and Ecofilm)

PLA

17
Q

How is Potatopak produced?

A

The waste water from the processing of potatoes for the production of chips and crisps etc contains starch

This water is fed through a starch extractor

Water can be reused and the dried starch can be processed by a high-speed pressure thermoforming machine that inserts powdered starch onto moulds

The starch is pressurised and ‘cooked’ into a rigid durable shape

18
Q

Properties of PLA/corn starch polymer

A

Food safe

UV resistant

Good aroma barrier

Low flammability

Compostable

19
Q

Issues with PLA/corn starch polymer

A

Can’t be recycled

Without enough oxygen and light PLA won’t decompose for decades

20
Q

PHA/PHB closed loop carbon cycle

A

The quantity of CO2 produced in the biomass process is the same as that absorbed by the corn - carbon neutral

Bacteria is encouraged to grow
Nitrogen deficiency develops
Bacteria absorbs carbon as a copolymer
Processed into PHA/PHB and then into products
End of useful life - degrades harmlessly in soil

21
Q

Properties of Biopol (PHB) and PHA

A

Insoluble in water and will sink

Similar tensile strength to PP

High melting point - 175 degrees C

More expensive and more time consuming to produce than traditional polymers

Low resistance to acids and alkalis

Low impact resistance

22
Q

Potatopak properties

A

Edible

Non-toxic and food safe

Able to be composted - will break down in 4 weeks

Cradle-to-cradle approach

Small amount of solid waste produced can be used to feed pigs

Produces no harmful gases in its production

23
Q

Negatives of potatopak

A

Still ongoing research into finding a suitable sustainable surface coating for protection of the starch

Starch can break down on exposure to hot liquids and some foods such as raw meats