all of year 10 Flashcards
what are the different types of bonding
- metallic
- ionic (metal & non-metal)
- covalent (non-metals)
- giant covalent
define metalic bonding
eletrostation attraction between rows of metal cations and a sea of delocalised electrons
explain is metals are malleable or soft
malleable and ductile because the layers of cations can slide
define ionic bonding
eletrostatic attraction between positive metal and negative non-metal ions
are ionically bonded materials malleable or soft
brittle (hard but easy to break)
define covalent bonding
electrostatic attraction between the bonding pair of electrons and bonded nuclei with weak intermolecular forces between molecules
what is an alloy
a mixture of two or more elements one of which is a metal
why are alloys stronger than metals
because alloys have different sized atoms so the arrangement is more irregular so it is harder to bend / snap as the irregular atoms do not easily move over each other
describe the reactivity down group one
the get more reactive as you go down
how do group 1 elements react with air
they all instantly tarnish in air due to oxygen producing a white oxide
what is the name given to group one elements
alkali metals
describe how lithium reacts with water
- moves on surface of water
- fizzes
- floats
- squeaky pop with flame
- universal indicator turns blue
describe how sodium reacts with water
- moves on surface of water
- fizzes
- floats
- squeaky pop with flame
- universal indicator turns blue
- melts into a ball
describe how potassium reacts with water
- moves on surface of water
- fizzes
- floats
- squeaky pop with flame
- universal indicator turns blue
- purple flame
- melts into a ball
- exploded
explain why group one metals get more reactive down the group
- the outer electron is further away from the nucleus
- there is less attraction = quicker transfer
- the atos has more shells so the outer electron is more easily lost
what are the procucts of a group 1 element and water
- metal hydroxide
- hydrogen
what is the formula for hydroxide
OH -
what is the formula for nitrate
NO3 -
what is the formula for carbonate
CO3 2-
what is the formula for sulphate
SO4 2-
what is the formula for hyrdrochloric acid
HCl
what is the formula for sulfuric acid
H2SO4
what is the formula for nitric acid
HNO3
what is the name given to group 7 elements
halogens
what are the gases in group 7
fluorine and chlorine
what are the liquid(s) in group 7
bromine
what are the solid(s) in group 7
iodine
how many electrons do halogens have
7
explain the reactivity trend in group 7
- less reactive down the group
- more shells of electrons
- outer shell electrons are less strongly attracted to the nucleus
- it is harder to gain electrons
what colour is fluorine
pale yellow gas
what colour is chlorine
green gas
what colour is bromine
red-brown liquid
what colour is iodine
dark gray solid
describe displacement in the halogens
a more reactive halogen will displace a less reactive halogen from a solution of its compound
will chlorine displace bromine
yes
will bromine displace iodine
yes
will iodine displace chlorine
no
what is a redox reaction
when oxidation and reduction occur at the same time in a reaction
what is oxidation
when a substance gains oxygen or loses electrons
what is reduction
when a substance loses oxygen or gains electrons
what is the oxidising agent
the substance that is reduced (loses oxygen)
what is the reducing agent
the substance that is oxidised (gains oxygen)
define an acid
produces H+ when dissolved in water, they are proton donors
what pH do acidic soutions have
<7
define a base
can neutralise an acid; they are proton acceptors
define an alkali
a soluble producing OH- ions when disolved in water
what pH do alkali solutions have
> 7
when will an indicator not work
if the solution already has a colour
what is the alternative to an indicator
a pH meter
what are the indicators and their colour change from acid to alkali
- litmus paper = red - blue
- methyl orange = red - yellow
- phenolphthalein = colourless - pink
- universal = red - orange - green - blue - purple
what type of solutions will metal oxides form
alkaline
what type of solutions will non-metal oxides form
acidic
what is the difference between a base and an alkali
bases aren’t soluble in water, alkalis are soluble in water
what type of salt will be formed with hydrochloric acid
a chloride
what type of salt will be formed with sulfuric acid
a sulfate
what type of salt will be formed with nitric acid
a nitate
when are salts fromed
when an acid reacts
what are the products formed from a metal and an acid
- salt
- hydrogen
what are the products formed from a metal oxide and an acid
- salt
- water
what are the products formed from a metal carbonate and an acid
- salt
- carbon dioxide
- water
what are the products formed from a metal hydroxide and an acid
- salt
- water
why don’t you react gorup 1 with acids
it is too dangerous
what are the two methods to form sulble salts
- excess solid
- titration
describe the excess solid method
- heat the sulfuric acid
- add balck copper oxide powder to excess and stir
- filter out excess copper oxide
- heat the blue copper sulfate solution until crystalisation point and leave to dry
- filter out the crystals and wash with distilled water
- leave to dry or dry between filter paper
describe a titration
- pipette alkali solution into a cronicle flask
- add a few drops of phenolphthalein indicator
- put acid into the burette
- acid is added to the alkali with swirling until the indicator changes colour from pink to colourless
- record your burette volume and repeat until concordant results are achieved
- repeat without indicator and heat till crystalisation etc for pure salt
what are concodant results
+ or - 0.1cm^2
how do you record a burette reading
with 2 decimal place
what is the equation fro neutrilisation
H+ (aq) + OH- (aq) -> H2O (l)
what is meant by the term precipitate
an insoluble salt made from two solutions
are sodium salts soluble or insoluble
soluble
are potassium salts soluble or insoluble
soluble
are ammonium salts soluble or insoluble
soluble
are nitrate salts soluble or insoluble
soluble
are chloride salts soluble or insoluble
soluble except for silver chloride and lead chloride
are sulfate salts soluble or insoluble
soluble except for lead, barium and calcium sulfate
are carbonate salts soluble or insoluble
insoluble except for sodium, potassium and ammonium carbonate
are hydroxide salts soluble or insoluble
insoluble excep for sodium, potassium and calcium hydroxide
describe the method of making an insoluble salt
- mix the two soluble salt solutions together
- precipitate forms
- filter out precipitate
- wash with cold water
- leave to dry in a warm oven
what is the chemical test and result for hydrogen
lit split
= squeaky pop
what is the chemical test and result for oxygen
glowing split
= relights
what is the chemical test and result for carbon dioxide
add acid and bubble through lime water
= goes ‘cloudy white’
what is the chemical test and result for chlorine gas
damp blue litmus paper
= may turn red then bleached white
what is the chemical test and result for ammonia gas
damp red litmus paper
= turns blue
what is the chemical test and result for water
white anhydrous copper sulfate
= turns blue
how do you test for solid metal ions
carry out a flame test
describe a flame test
- dip a nichrome wire into an unreactive, colourless acid
- dip it into ionic solid
- put it in a roaring bunsen flame so the colour of flame will not interfere
what colour flame will lithium produce
red
what colour flame will sodium produce
yellow
what colour flame will potassium produce
lilac
what colour flame will calcium produce
red-orange
what colour flame will copper produce
blue-green
how do you test for metal ions in a solution
add NaOH
what is the result of NaOH added to copper
blue precipitate
what is the result of NaOH added to iron (II)
sludgy green precipitate
what is the result of NaOH added to iron (III)
reddish brown precipitate
how do you test for the halogen non-metal ions
- add HNO3
- add AgNO3
what precipitate is formed from chloride
white precipitate
what precipitate is formed from bromide
cream precipitate
what precipitate is formed from iodine
yellow precipitate
how do you test for sulphate non-metal ions and what is the result
- add HCl
- add BaCl2
= white precipitate
what are the rules when doing an ionic equation for a precipitate
- write the formula of the precipitate on the right
- write the ions that make it up on the left
- balance and add state symbols
what is the general formula of an alkane
CnH2n+2
what is the general formula of an alkene
CnH2n
what is the general fromula of an alcohol
CnH2n+1OH
what is the meant by the term empricial formula
the simplest whole number ratio of atoms of each element in a compound
what is the stem for a hydrocarbon with one carbon atom
meth-
what is the stem for a hydrocarbon with two carbon atoms
eth-
what is the stem for a hydrocarbon with three carbon atoms
prop-
what is the stem for a hydrocarbon with four carbon atoms
but-
what is meant by the term hydrocarbon
a molecule made up of only carbon and hydrogen atoms
what is meant by the term saturated
a molecule only containing single bonds between carbon atoms
what is meant by the term unsaturated
a molecule containing carbon = carbon double bonds
what is meant by the term isomer
molecule with the same molecular formula but different structual formulae
what are the rules for drawing an isomer of a hydrocarbon
- take one carbon off the long chain
- re-bond that carbon to the orignal chain at least one carbon from the end
what is crude oil
a mixture of molecules (mainly hydrocarbons)
what is the process whihc spereates out crude oil
fractional distilation
describe fractional distilation of crude oil
- crude oil is heated up it vapourises
- vapours ride up the column and condense at temperature just below their boiling point
- they condense into different groups called fractions
- they column is cooler at the top than the bottom
- the larger molecules with higher boiling points condense at the bottom
what are the products from fractional distilation from top of the column to the bottom
- refinary gases
- gasoline (petrol)
- kerosene
- diesel
- fuel oil
- bitumen
what are the physical properties of the longer chain hydrocarbons
- more viscous
- more yellow/orange in colour
why is catalytic cracking neccessary
because short-chain hydrocarbons are at higher demand as they are easily ignited so can be used for fuels but there is a greater supply of long-chain hydrocarbons
what is catalystic cracking
the process of breaking down long-chain hydrocarbons into short-chain hydrocarbons
what conditions are needed for catalytic cracking
- 600-700 degrees celcius
- catalyst
what are the two options for a catalyst for catalytic cracking
- alumina
- silica
what type of reaction is combustion
exothermic
what are the two types of combustion
- complete
- incomplete
what are the conditions and products for complete combustion
- lots of O2
- releases CO2 and H2O
what are the conditions and products for incomplete combustion
- limited O2
- releases CO and H2O
what is the apparatus for combustion
a u-tube with anydrous CuSO4
what are the main pollutants from burning fuels and combustion
- CO2 = greenhouse gas = global warming
- CO = toxic = prevents blood carrying oxygen = death
- NO, NO2 = acid rain
are alkenes saturated or unsaturated
unsaturated
when are alkene produced
when large hydrocarbon molecules are cracked into samller hydrocarbon molecules
what are alkenes used to produce
plastics
how can you distinguish between an alkane and alkene
by reacting it with bromine water
how does an alkene react with bromine water
it rapidly decolourises from orange to colourless
- the c=c breaks
- the Br joins the molecule
what type of reaction is an alkene with bromine water
addition reaction
how does an alkane react with bromine water
with intense UV light
- one H substitutes for one Br
- producing the molecule and HBr
what type of reaction is an alkane with bromine water
substitution reaction
what is a monomer
a small molecule that can be added together by breaking the double bond
what is a polymer
long, saturated molecule formed from monomers
explain the problems wiht using polymers
- they are inert (unreactive) as they have strong covalent bonds
- they do not biodegrade
- when burnt they produce toxic gases
desribe how you draw a polymer
- take the functional group (c=c)
- break the double bond
- draw two horazontal lines to show continued
- draw two brackets around
- copy the atoms on the carbons
- add an n outside the braket
what must alcohols contain
an OH
how do you purify ethanol from fermentation
by distilation
what is distilation
evapouration followed by condensation to concerntrate ethanol
what is ethanol used for
- make alcoholic drinks
- cars
how can you make ethanol
- fermentation
- direct hydration
what is the equation for fermentation
C6H12O6 -> 2C2H5OH + 2CO2
glucose -> ethanol + carbon dioxide
what is the equation for direct hydration
C2H4 + H2O -> C2H8OH
ethene + water -> ethanol
what is the functional group of a carboxylic acid
COOH
what must a carboxylic acid contain
COOH
what type of bonds do carboxylic acids have between their one oxygen
a double bond
what do carboxylic acids end in
-anoic acid
what is this molecule
ethanoic acid
what is this molecule
methanoic acid
when reacted what charge does a carboxylic acid have
-
what forms when a carboxylic acid reacts with a metal, eg ethanoic acid
the metal ethanoate & hydrogen
what is added as a catalyst when making esthers
sulphuric acid
what colour pH would carboxylic acids be
orange
what are esthers used in the industry for
perfumes and flavourings
what reacts together to form an esther
a carboxylic acid and an alcohol
what would the esther be called made by propanoic acid and methanol
methly propanoate
what conditions are used when making esthers
H2SO4 and heat
what is the other product made when esthers are made
water
how are carboxylic acids formed
- by alcohols being oxidised
- microbial oxidation
what carboxylic acid does vinegar contain
ethanoic acid
what does volatile mean
that they turn innto gases quickly
are esthers volatile
yes
how do you make esthers in the lab
- add a few drops of concentrated sulfuric acid to a boiling tube with a dropping pipette
- add 10 drops of ethanoic aci
- add equal volume of ethanol
- place in beaker of water - on tripod
- heat with bunsen burner into boiling
- after 1 min remove tube and allow to cool
- pour into test tube if sodium carbonate and mix
- layer of esther will form on solution
what is the oxidising agent for alcohols to carboxylic acids
potassium dichromate(VI) in diulte sulfuric acid
what is the colour change when ethanol reacts with potassium dichromate in diulte sulfric acid
orange to green