Alkenes Flashcards

1
Q

Alkenes are…

A

Unsaturated hydrocarbons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What does a double covalent bond have that is important

A

High electron density, restricts rotation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is the test for unsaturation

A

Add drops of bromine water, which should turn from orange to colourless if the substance is unsaturated

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Reactivity of addition polymers

A

Unreactive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Uses of poly(chloroethene)

A

Pipes, bottles, insulation on cables

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why are addition polymers unreactive

A

Their backbone consists of strong, non-polar C-C bonds and are saturated. This means that they are not biodegradable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Explain the nature of intermolecular forces between polyalkane molecules

A

Since the hydrocarbon chains are often very long, the Van der Waal’s forces between the chains are often very strong and the polymers have relatively high melting and boiling points

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is a plasticiser for

A

Plasticisers are used to make a material like PVC softer and more flexible. They decrease the attraction between polymer chains by staying between the chains and allowing them to slide across each other

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Conditions for addition polymerisation

A

High pressure, high temperature, O2 as the catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is the repeating unit of addition polymers

A

A part of a polymer whose repetition would produce the complete polymer chain

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is the difference between a monomer and a repeating unit

A

Monomer is the molecule before polymerisation, repeating unit is the molecule after polymerisation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is stereoisomerism

A

Same molecular and structural formula, but different spatial arrangement of atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is the monomer in PVC

A

Chloroethene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Uses of PVC before and after plasticising

A

Drainpipes before and plastic aprons after

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is a monomer

A

Small molecules, which bond together to form a polymer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

How to produce alcohols from alkenes

A

React water with an alkene at 300 degrees, 70atms with conc. H3PO4

17
Q

How to know the major product in the electrophilic addition of unsymmetrical alkenes

A

The more electronegative atom bonds with the carbon, which is bonded with the most carbons. This is a more stable carbocation. Tertiary > Secondary > Primary

18
Q

What is an electrophile

A

An electron pair acceptor

19
Q

Give an example of a plasticiser

A

Ester

20
Q

What is the functional group isomer of an alkene

A

Cycloalkane

21
Q

What cracking produces alkenes

A

Thermal cracking. High temperature and high pressure.

22
Q

Why does bromine, a non-polar molecule, react with an alkene

A

The carbon- carbon double bond has a high electron density, which causes an induced dipole in bromine