alkanes and haloalkanes Flashcards

1
Q

what are alkanes

A

They are saturated hydrocarbons
they are molecules made of only hydrogen and carbon atoms
each of their carbon atoms forms four single bonds

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2
Q

outline the process of fractional distillation

A

crude oil vaporised at around 350 degrees celcius
vaporised crude oil goes into borrom of fractioning column rises up through the trays
largest hydrocarbons don’t vaporise at all they just run to the bottom and form a residue
as crude oil vapour goes up fractioning column it gets cooler
the fractions condense at their boiling points and are collected
alkanes with lowest boiling points don’t condense and are collected as gases at the top

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3
Q

what do longer chain hydrocarbons undergo to form shorter chain hydrocarbons and alkenes that are more useful

A

longer chain hydrocarbons undergo cracking to form shorter chain hydrocarbons and alkenes

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4
Q

what does cracking involve

A

the breaking of C-C bonds in the alkanes

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5
Q

what are the two types of cracking

A

thermal cracking

catalytic cracking

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6
Q

what are the conditions of thermal cracking

A

high temperature- 1000 degrees celcius

high pressure around 70atm

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7
Q

what are the products of thermal cracking

A

lots of alkenes

useful for production of polymers

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8
Q

what are the conditions of catalytic cracking

A

zeolite catalyst
slight pressure
high temperature of around 500 degrees celcius

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9
Q

what are the products of catalytic cracking

A

aromatic hydrocarbons

alkanes needed to produce motor fuels

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10
Q

what are the benifits of using a catalyst in catalytic cracking

A

cuts costs

reactions can be done at a low pressure and lower temperature

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11
Q

when is nitrogen monoxide produced

A

when the high pressure and temperature in a car engine causes the nitrogen and oxygen atoms in the air to react together

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12
Q

what are the two reactions of nitrogen and oxygen in the engine of a car

A

N2 + O2—— 2NO

2NO + 02—— 2NO2

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13
Q

what are the two reactions that occur in a catalytic converter of a car

A

2NO —– N2 + O2

2NO + 2CO—– N2 + 2CO2

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14
Q

how is sulfur dioxide formed

A

when a fossil fuel containing sulfur impurities is burnt

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15
Q

what is a photochemical reaction

A

a reaction started by UV light

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16
Q

what is a free radical

A

particle with an unpaired electron

17
Q

what is the function of ozone

A

it absorbs ultra violet radiation from the sun

18
Q

what are haloalkanes

A

an alkane with at least one halogen in place of a hydrogen atom

19
Q

why are haloalkanes polar

A

as halogens are generally more electronegative than carbon so carbon halogen bonds are polar

20
Q

what is a nucleophile

A

an electron pair donor

21
Q

what is the trend of reactivity of haloalkanes

A

it increases with decreasing bond enthalpy as the bond gets weaker

22
Q

what are the conditions for elimination reaction

A

hot hydroxide ions dissolved in ethanol