6.1.2: Carbonyl compounds Flashcards

1
Q

What is the carbonyl group?

A

C=O

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2
Q

What is the functional group and general formula for

an aldehyde?

A

RCHO (C double bonded to O, single bond to H and R)

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3
Q

What is the functional group for a ketone?

A

RCOR’ (C double bonded to O)

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4
Q

How do you name aldehydes?

A

-al suffix (C=O is on the end of a chain)

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5
Q

How do you name ketones?

A

-one suffix (designate number for which

carbon C=O is on)

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6
Q

What kind of intermolecular forces do molecules with

the carbonyl group have? Why?

A

Permanent dipole-dipole due to the polar C=O

bond (O is ∂-)

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7
Q

How soluble are they in water? What influences

solubility?

A

Yes - form hydrogen bonds between water
molecules and oxygen of C=O. As C chain length
increases, solubility decreases.

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8
Q

Which bond in carbonyl compounds is usually

involved in reactions? Why?

A

C=O, due to the polarity of the bond (large

difference in electronegativity between C and O)

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9
Q

What is the strongest bond in carbonyl compounds?

A

C=O

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10
Q

Why is the addition of HCN important?

A

Increases the length of the carbon chain by one
carbon atom allowing more useful molecules to
be made.

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11
Q

Will the product of HCN added to a carbonyl

compound have optical isomers? Why?

A

Yes they will. In the aldehyde/ketone, the
carbonyl carbon is planar, so the :CN- can attack
from either above or below, forming two enantiomers.

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12
Q

What is the name of the product when HCN is added

to a carbonyl compound?

A

Hydroxynitriles (have OH and CN groups)

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13
Q

What is Fehling’s solution? What colour is it?

A

Copper complex ions, blue

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14
Q

What happens when an aldehyde is added to

Fehling’s solution?

A

Reduced to Cu+ ions → colour change to brick red ppt

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15
Q

What happens when a ketone is added to Fehling’s

solution?

A

No visible change → stays blue

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16
Q

How do you test for a carbonyl compound?

A

Use Brady’s reagent - 2,4-dinitrophenylhydrazine

If a carbonyl compound is present an orange precipitate is formed

17
Q

What is in Tollens’ reagent?

A

Silver complex ions in colourless solution.

18
Q

What happens when an aldehyde is added to

Tollen’s reagent?

A

Silver mirror forms as Ag+ reduced to Ag(s)

19
Q

What happens when a ketone is added to Tollen’s

reagent?

A

No visible change

20
Q

What is another oxidising agent for alcohols and aldehydes? What change in colour does this undergo?

A

Acidified potassium dichromate (VI) - H2SO4 and

K2Cr2O7. Colour change from orange to green.

21
Q

What is a reducing agent for aldehydes and

ketones? What ions does this release in solution?

A

NaBH4 (sodium tetrahydridoborate (III)), releases an H- ion

22
Q

Write an equation for the reduction of pentan-2-one

and for 3-methylbutanal.

A

CH3COCH2CH2CH3 + 2[H] → CH3CH(OH)CH2CH2CH3

CH3CH2CH2 (CH3)CHO + 2[H] → CH3CH2CH2(CH3)CH2OH

23
Q

How do you convert an aldehyde to form a carboxylic acid?

A

Oxidation of aldehydes using Cr2O7

2-/H+ (i.e. K2Cr2O7/H2SO4)