5.1.2: How far? Flashcards

1
Q

What does it mean when a reaction is at equilibrium?

A

The rate of forward and reverse reactions are equal

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2
Q

What are the methods that can be used to measure equilibrium?

A

● Measure change in colour or colour intensity using colorimeter
● Use pH probe
● Measure electrical conductivity
● Titration - used when equilibrium is slow so that titration can be completed before there is much change in equilibrium mixture

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3
Q

What does mole fraction mean?

A

The amount of a given component in a given reaction mixture

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4
Q

Write the equation used to calculate mole fraction

A

Mole fraction = number of moles of

substance A / total number of moles of all substances

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5
Q

What does partial pressure mean?

A

The pressure exerted by a single species

in a reaction vessel

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6
Q

What is the symbol for partial pressure?

A

P

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7
Q

Write the equation used to calculate partial pressure

A

Partial pressure = mole fraction x total pressure

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8
Q

What is the relationship between concentration of a substance and its partial pressure?

A

Concentration of a substance is proportional to its partial pressure

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9
Q

What are the 3 common units of pressure used in chemistry?

A

● Pascals
● Atmospheres
● Newtons per square metre

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10
Q

What type of brackets are used in Kc expressions?

A

Square brackets

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11
Q

What type of brackets are used in Kp expressions?

A

Round brackets

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12
Q

How do you calculate the units for Kp?

A

Write out the units for the partial pressures in the
same arrangement as the Kp equation and cancel
out/multiply together.
Usually in Pa, kPa, atm etc. DO NOT CHANGE
UNITS

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13
Q

What is the symbol of equilibrium constant?

A

K

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14
Q

What does it mean when K is greater than 1?

A

● Reaction favours product

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15
Q

What does it mean when K is lesser than 1?

A

The reaction favours reactants

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16
Q

What is the effect of increasing temperature on K?

A

Equilibrium shifts to the direction of endothermic reaction

17
Q

What is the effect of decreasing temperature on K?

A

Equilibrium shifts to the direction of

exothermic reaction

18
Q

What is the only factor that affects K?

A

Temperature

19
Q

What is the effect of increasing temperature on K for a forward endothermic reaction?

A

K increases as temperature increases

20
Q

What is the effect of increasing temperature on K for a forward exothermic reaction?

A

K decreases as temperature increases

21
Q

What effect does catalyst have on K ?

A

Catalysts does not affect the position of
equilibrium, they only have an effect on
the rate of reaction