5.3 enthalpy, entropy and free energy Flashcards
mean bond enthalpy
average enthalpy change when one mole of a given bond is broken in a range of molecules
standard enthalpy of formation
enthalpy change when one mole of a substance is formed from elements under standard conditions
standard enthalpy of combustion
enthalpy change when one mole of a substance is completely burnt in oxygen
standard enthalpy of atomisation
enthalpy change when one mole of gaseous atoms form from elements in the standard state
enthalpy change of hydration
enthalpy change when one mole of gaseous ions from aqueous ions
standard enthalpy change of solution
enthalpy change when one mole of solute forms a solution
first ionisation energy
the energy required to remove one electron from each of one mole of gaseous atoms to an infinite separation.
first electron affinity
enthalpy change when one mole of a gaseous atoms form one mole of gaseous ions with a negative charge
lattice enthalpy of formation
enthalpy change when one mole of a solid ionic compound is formed from gaseous ions
lattice enthalpy of dissociation
enthalpy change when one mole of a solid ionic compound is dissociated into gaseous ions
what is entropy
how disordered a reaction is
positive gibbs free energy value:
not feasible at that temp
negative gibbs free energy value:
not feasible at that temp