4.3 alcohols + haloalkanes Flashcards

1
Q

how are alcohols completely soluble

A

polarity of alcohols allows hydrogen bonds to form

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2
Q

products of combustion of alcohols

A

carbon dioxide and water
exothermic

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3
Q

what is a nucleophile

A

atom with a negative charge/can donate a lone pair of electrons

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4
Q

what do 2º alcohols oxidise to and how

A

ketones under reflux with potassium dichromate

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5
Q

what do 1º alcohols fully oxidise to and how

A

carbox acids under reflux with potassium dichromate

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6
Q

what do 1º alcohols oxidise to?

A

aldehydes by distilling off with potassium dichromate

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7
Q

how can you form an alkene and water from an alcohol?

A

dehydration to remove -OH an H by heating uner reflux with acid (H2SO4/H3PO4)

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8
Q

how can you form a haloalkane from an alcohol?

A
  1. substitute the OH with a halide ion under reflux with acid and sodium halide
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9
Q

what happens when a haloalkane reacts with aq NaOH or KOH?

A

the OH- is a nucleophile and is substituted for the halogen

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10
Q

strongest and weakest carbon-halogen bond?

A

strongest = C-F
weakest = C-I

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11
Q

ozone formula

A

O3

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12
Q

what happens when CFCs enter the atomosphere

A

the UV radiation causes the C-Cl bond to break and a Cl radical is formed

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13
Q

initiation reaction of CFC’s

A
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14
Q

propagation reactions of CFCs

A
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15
Q

termination reaction of CFCs

A
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