4.3 alcohols + haloalkanes Flashcards
how are alcohols completely soluble
polarity of alcohols allows hydrogen bonds to form
products of combustion of alcohols
carbon dioxide and water
exothermic
what is a nucleophile
atom with a negative charge/can donate a lone pair of electrons
what do 2º alcohols oxidise to and how
ketones under reflux with potassium dichromate
what do 1º alcohols fully oxidise to and how
carbox acids under reflux with potassium dichromate
what do 1º alcohols oxidise to?
aldehydes by distilling off with potassium dichromate
how can you form an alkene and water from an alcohol?
dehydration to remove -OH an H by heating uner reflux with acid (H2SO4/H3PO4)
how can you form a haloalkane from an alcohol?
- substitute the OH with a halide ion under reflux with acid and sodium halide
what happens when a haloalkane reacts with aq NaOH or KOH?
the OH- is a nucleophile and is substituted for the halogen
strongest and weakest carbon-halogen bond?
strongest = C-F
weakest = C-I
ozone formula
O3
what happens when CFCs enter the atomosphere
the UV radiation causes the C-Cl bond to break and a Cl radical is formed
initiation reaction of CFC’s
propagation reactions of CFCs
termination reaction of CFCs