5.1.3 Buffers and Neutralisation Flashcards
buffer solution
a system that minimises pH changes when small amounts of acid or a base are added
what 2 components does buffer solution contain
weak acid
conjugate base
what does the weak acid in a buffer solution remove
added alkali
what does the conjugate base in a buffer solution remove
added acid
does the pH change as the buffer works
yes it doesnt remain completely constant
what happens if you add acid to a buffer
[H+] increases
H+ react with conjugate base A-
equilibrium position shifts left to remove most H+ ions
what happens to buffer if you add a alkali
[OH-] increases
H+ react with OH- to form water
HA dissociates shifting equilibrium position to the right to restor the [H+]
whats true when [HA]=[A-]
pH of buffer is same as pKa value of HA
operating pH is over about 2 pH units centred at pH of the pKa
Ka=
[H+][A-] / [HA]
equation to work out [H+] of buffer
Ka x [HA] / [A-]
what is the pH range of blood
7.35 - 7.45
how to find equivilance point
centre of the vertical point of the pH titration curve
what is the equivilance point
the volume of one solution that exactly reacts with volume of other solution
what colour is a weak acid in methyl orange
red
what is the colour of a conjugate base in methyl orange
yellow