5.1.2 How Far Flashcards

1
Q

how to work out units for Kc

A

substitute units into Kc expression
cancel common units
ones left are units
write on single line

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2
Q

Homogeneous equilibria

A

contains equilibrium species that all have the same state or phase
e.g all species are gases

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3
Q

Heterogeneous equilibria

A

contains equilibrium species that have different states or phases
e.g some are solid, some are gases

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4
Q

what states are included in Kc

A

aqeous
gas

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5
Q

what happens to Kc for heterogenous equilibria

A

concentrations of solid and liquids are contant so they are ommited from the equation
only include (aq) and (g) in Kc equation

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6
Q

what is Kp

A

the equilibrium constant in terms of partial pressure

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7
Q

mole fraction for A

A

number of moles of A / total number of moles in gas mixture

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8
Q

partial pressure of A

A

mole fraction of A X total pressure

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9
Q

Kp equation

A

p(products) / p(reactants)

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10
Q

suitable units for partial pressure

A

kilopascals - kPa
pascals -Pa
atmospheres - atm

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11
Q

what state must the substance be to be in the Kp expression and why

A

gas as only gases have partial pressures

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12
Q

what causes K to change

A

temperature

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13
Q

wheres equlibrium if K =1

A

halfway between reactants and products

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14
Q

wheres equlibrium if K =100

A

well in favour of products

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15
Q

wheres equlibrium if K =0.01

A

well in favour of reactants

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16
Q

what happens to K if the reaction is exothermic and you increase the temperature

A

decreases

17
Q

what is Kc

A

equilibrium constant

18
Q

what happens to equilibrium yield of products if the reaction is exothermic and you increase the temperature

A

decrease yield

19
Q

what happens to Kp if you increase the temperature and its an exothermic reaction

A

Kp decreases

20
Q

if forward reaction is endothermic what happens to K if you increase the temperature

A

equilibrium constant increases

21
Q

if forward reaction is endothermic what happens to equilibrium yield of products if you increase the temperature

A

increases yield

22
Q

if forward reaction is endothermic what happens to Kp if you increase the temperature

A

Kp increase

23
Q

how does changes in concentration and pressure affect equilibrium constants

A

its unaffected as the equilibrium constant not changing causes the equilibrium shift

24
Q

How does a catalyst affect equilibrium constants

A

they affect the rate of reactioon but not the position of equilibrium
they speed up forward and backwards reactions by the same factor