3.2.2 - group 2 the alkaline earth metals Flashcards

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1
Q

Trend in atomic radius down group 2

A

Atomic radius increases as you go down the group

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2
Q

Why does atomic radius get bigger Down group 2

A

Increased number of e-
Increased number of shells

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3
Q

Electronegativity down group 2 trend ?

A

Decreases down group 2

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4
Q

Why does electronegativity decrease down group 2

A

Increased number of shells
Increased dist from nucleus
Nucleus cannot attract electrons in a covalent bond so easily

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5
Q

Trend in mp down group 2

A

Melting points decrease down group 2

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6
Q

Why does melting point decrease down group 2

A

As you go down the group
Metal becomes bigger so e- further away from positive ions and thus have less electrostatic attraction so less energy needed to overcome bonds

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7
Q

Trend in ionisation energies down group two

A

First ionisation energy decreases down the group

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8
Q

Ionisation energy decreases down group 2 because

A

Each element down group 2 has an extra electron shell compared to the one above
The extra inner shells shield the outer e- from attraction of the nucleus
Extra shell outer e- further from nucleus, weaker attraction so e- can be removed more easier

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9
Q

Reactivity down group 2

A

As you go down the group reactivity increases

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10
Q

Group 2 metals more reactive down the groupwhy

A

As you go down the group first ionisation energy decreases
This is due to increasing atomic radius and shielding effect
When group 2 metals react they loose e-., the easier to loose e- (lower the first nd second ionisation energy) the more reactive the element so reactivity increases down the group

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11
Q

Group 2 metals + water gives

A

Metal hydroxide + hydrogen

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12
Q

When group 2 metals react with water the water acts as

A

Oxidising agent

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13
Q

Trends in solubility of hydroxides down group 2

A

Hydroxides increase in solubility down the group

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14
Q

Trend in solubility of sulphites down group 2

A

Sulphates decrease in solubility down the group

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15
Q

Although sulfates decrease in solubility did a group they are still somewhat soluble what is the anomaly

A

Barium sulfate (BaSO4)

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16
Q

Baso4 forms a _____ precipitate

A

White precipitate

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17
Q

Use of barium sulfate not in med

A

Used to test for sulphate ions

18
Q

Test for sulphate ions

A

Add acidified barium chloride (Bacl2)
A white ppt of barium sulfate will form (+ve test result)

19
Q

Why is acidified barium chloride used in test for sulphate ions

A

To remove ions that will also produce white ppt giving false positive

20
Q

Use of barium sulfate

A

Barium meals to absorb x rays. It’s insoluble and not absorbed by the body so it’s harmless.

21
Q

Due to greater reactivity of barium its …

A

Stored in oil to keep out of contact with air

22
Q

Grouo 2 metals and oxygen form

A

Solid metal oxides that are white in colour

23
Q

Mg and cold water form ..
Give equation

A

Magnesium hydroxide and hydrogen gas

Mg (s) + 2 H2O (l) → Mg (OH)2 (aq) + H2 (g)

24
Q

Mg reacts w steam produces …
Observation…
Equation…

A

Hot magnesium reacts with steam vigorously producing a bright light and
forming magnesium oxide and hydrogen gas.
Mg (s) + H2O (g) → MgO (s) + H2 (g)

25
Q

Reactivity of group 2 metals w water down the group

A

Down the group, the metals react more rapidly with water

26
Q

Trend in ph of hydroxide solutions down the group and why

A

The pH of hydroxide solutions increases down the group. This is
because of the solubility of hydroxides in water increases down
the group

27
Q

Solubility of (MgOH)2

A

Almost insoluble

28
Q

Use of mgoh2

A

Aid indigestion
By neutralising excess stomach acids

29
Q

Use of (CaOH)2

A

agriculture to neutrialise acid soils

30
Q

Is caoh 2 soluble or insoluble

A

Soluble
More than mgoh2, more hydroxide ions prod so higher ph more alkaline

31
Q

Magnesium is used in extracting ______ from its ore

A

Titainium

32
Q

1st step of extracting titanium from its ore

A

Titanium oxide is converted to titanium(IV) chloride by heating it with chlorine
and coke (a form of carbon) at 1000 ⁰C
● TiO2 + 2Cl2 + 2C → TiCl4 + 2CO

33
Q

2nd step of extracting tit w mg

A

Titanium iv chloride is reduced by mg
Purified by frac dist
TiCl4(l) + 2Mg(s) → Ti(s) + 2MgCl2(s)

34
Q

What group 2 compounds are used to remove sulfur dioxide from flue gases

A

Calcium oxide
Calcium carbonate
Alkalis

35
Q

Name of process removing so2 w cao or caco3

A

Wet scrubbing

36
Q

Wet scrubbing equation for cao

A

CaO (s) +2H2o (l) + so2 (G) —> CaSo3 (s) + 2H2O (l)

37
Q

Wet scrubbing equation for caco3

A

CaCO3(s) + 2H2O (l) + SO2 (g) —> CaSO3 (s) + 2H2O (l) +CO2(g)

38
Q

Group 2 elements loose ____ electrons when they react

A

2

39
Q

Half equation when mg is dissolved in naoh to test solubility

A

Mg2+ (aq) + 2OH- (aq) ~~~> Mg(OH)2 (s)

40
Q

Mg(OH)2 described as

A

Sparingly soluble

41
Q

Observation when Ba(OH)2 dissolves

A

No visible chjage
Completely soluble

42
Q

Calcium sulfate equation when dissolved in water

A

Ca2+ (aq) + SO4 ^2- (aq) —> CaSo4 (s)