05 - states of matter Flashcards

1
Q

gas particles are:

A

. far apart (so can be compressed)
. are randomly arranged
. can move freely from place to place, in all directions

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2
Q

liquid particles are:

A

. close together (so have a fixed volume, can only be compressed slightly)
. mostly randomly arranged
. limited movement from place to place

LIQUIDS TAKE THE SHAPE OF THE CONTAINER

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3
Q

solid particles are:

A

. touching each other (can’t be compressed)
. usually in a regular arrangement
. can’t change positions with each other, only vibrate

SOLIDS HAVE A FIXED SHAPE AND VOLUME

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4
Q

what are the types of structures found in elements and compounds:

A

. simple molecular/simple atomic
. giant ionic
. giant metallic
. giant molecular (noble gases thought of having this structure, although they exist as isolated atoms)

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5
Q

what is the kinetic theory of gases?

A

. the theory that particles in gases liquids are in constant movement

. used to explain the effect of temperature and pressure on the volume of a gas as well as the rates of chemical reactions

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6
Q

what are the assumptions made by the kinetic theory of gases?

A

. gas molecules move rapidly and randomly
. dist. betwesn gas molecules&raquo_space;> diameter of molecules SO they have nelegible volume
. no intermolecular forces of attraction or repulsion between the molecules
. collisions between particles are elastic (no kinetic energy lost in collisions)
. temperature of the gas is related to avg. ke of the molecules

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7
Q

what is an ideal gas?

A

a gas whose volume varies in proportion to the temperature and in inverse proportion to the pressure

noble gas approach ideal gas behavior (due to their low intermolecular forces)

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8
Q

what is a real gas?

A

a gas that does not obey the ideal gas law, especially at low temps and high pressures

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9
Q

volume of a gas depends on:

A

. pressure in Pa
. temperature in K

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10
Q

volume relation to pressure?

A

volume = 1/pressure

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11
Q

volume relation to temperature?

A

volume is directly proportional to temp

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12
Q

in what ways do real gases not ovbey the kinetic theory?

A

. not zero attraction between molecules
. volume of molecules are not neligible

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13
Q

under high pressure and low temp, real gases:

A

. molecules are close to each other
. volume of the molecules not negligible
. there are id id or pd pd forces between molecules
. attractive forces pull mols towards each toher and away from container
. pressure lower than expected
. effective volume of gas is smaller than ideal gas

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14
Q

whats the formula?

A

pV=nRT

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15
Q

pV=nRT stands for?

A

p = pressure in Pa
V = colume of gas in cm3
n = no. of moles of gas
R = gas constant (8.31 J K-1 mol-1)
T = temperature in K

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16
Q

celsius to kelvin

A

+ 273

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17
Q

methods of calculating relative molecular mass?

A

. use a mass spectrometer, accurate
. use general gas eq, less accurate

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18
Q

melting for solids?

A

. energy transferred makes particles vibrate more vigorously
. forces of attraction between particles weaken
. solid beocmes liquid at its melting point

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19
Q

what is the melting point of a solid?

A

the temperature at which it changes to a liquid at 1atm

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20
Q

to melt ionic compounds, need…

A

high temp (strong bonds)

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21
Q

to melt molecular solids, need…

A

low temperature (weak intermolecular forces between particles)

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22
Q

what is vaporisation?

A

the change in state when a liquid changes to vapour

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23
Q

when heating a liquid?

A

. particles move faster
. forces for atrraction between particles weaken
. particles with most energy escape first
. liquid evaporates (at temp below boiling point)
. forces weaken for all the particles to become completely free from each other
. liquid boils at boiling point

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24
Q

what enthalpy change of vaporisation?

A

the energy required to change one mole of liquid to one mole of gas

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25
Q

what is condensation?

A

the change in state when a vapour change to a liquid

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26
Q

are chnages in states reversible?

A

YES

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27
Q

what is vapour pressure?

A

the pressure exerted by a vapour in equilibrium with a liquid

28
Q

as vapour pressure increases, temp increases because..

A

. gas particles have more ke
. particles move faster and overcome intermolecular forces of attraction more easily

29
Q

what is the boiling point of a liquid?

A

the temperature at which it chnage to a gas at one atm

temperature at which vapor pressure = atmostpheric pressure

30
Q

1 atmosphere =

A

101 325 Pa

31
Q

why do crystals have a regular structure?

A

due to the regularly packed particles within the crystals - called a crystal lattice

32
Q

what is a lattice?

A

a regularly repeatinv arrangement of ions, atoms or molecules in 3D

33
Q

ionic lattices?

A

AKA giant ionic lattices
. depends on ion sizes
. MgO and NaCl have cubic lattices

34
Q

ionic compound properties?

A

. hard - takes lot of energy to stratch surface, strong attractive forces
. brittle - may split if hit in same direction as ion layers, ions may be displaces and same charge ions come together, repulsion
. high mp and bp - strong attraction, increase with charge density (more attraction in 2+ and 2- than + and - )
. water soluble - can form ion-dipole bonds
. only conduct electricity when molten or in solution

35
Q

metals conduct electricity due to…

A

delocalised electrons

36
Q

ionic giant structures conduct when liquid/aq solution due to…

A

mobile ions

37
Q

metallic lattices?

A

. ions surrounded by a sea of electrons
. often in hexagonal layers or in a cubic arrangement
. malleable and ducile - forces acr in all directions, so bonds easily reform when layers slide
. high tensile strength and hardness - strong attraction forces

38
Q

what is an alloy?

A

a mixture of two or more metals or a metal with a non metal

39
Q

brass

A

70% copper
30% zinc

40
Q

why is brass stronger than copper

A

difference in Zn and Cu ion sizes makes lattice arrangement less regularly

41
Q

pure aluminium properties

A

. softer than many metals
. ductile
. high electrical and thermal conductivity
. low strength

42
Q

aluminium alloys properties

A

. lightweight
. strong
. corrosion resistant

43
Q

aluminium alloy uses

A

. aircraft bodies
. cylinder blocks of car engines
. bicycle frames

44
Q

bronze

A

alloy of copper and tin

45
Q

simple molecular lattices

A

. can form crystals
. ice forms crystalline lattices
. iodine has low melting point, weak im forces

46
Q

giant molecular/covalent structure

A

. structures having a 3D network of covalent bonds throughout the whole structure
. have high mps and bps - lots of covalent bonds
. eg: graphite, diamond, silicon dioxide

47
Q

what are allotropes?

A

different crystalline or moecular forms of the same element, eg graphite and diamond for carbon

48
Q

graphite properties:

A

. high mp and bp - strong covalent bonding
. soft - forces between carbon is weak, layers easily flake
. good electrical conductor - has free electrons

49
Q

graphite structure

A

. c atoms arranged in planar layers
. within layers, c atoms in hexagons

ONE C TO THREE C

. fourth electrons of occupies p orbital
. p orbitals overlap sideways
. cloud of delocalised electrons
clouds join form extended delocalised rings of electrons

50
Q

diamond properties

A

. high mp and bp - strong covalent bonds
. hard - hard to break 3D network of strong covalent bonds
. doesn’t conduct electricity - all four electrons bonded, no free
. good heat conductor

51
Q

diamond structure?

A

ONE C TO FOUR C

. tetrahedral arrangement
. network of C atoms extends unbroken
. crystalline structure

52
Q

artificial diamond

A

. too small of jewelry
. used for drill tips
. made by heating other forms of C under high pressure

53
Q

silicon IV oxide

A

. many forms
. found in mineral quartz
. structure and properties to diamond
. forms hard, colourless crystals with high mp and bp
. doesn’t conduct electricity
. largely sand

ONE SI TO FOUR O
ONE O TO TWO SI

54
Q

silicon IV oxide

A

. many forms
. found in mineral quartz
. structure and properties to diamond
. forms hard, colourless crystals with high mp and bp
. doesn’t conduct electricity
. largely sand

ONE SI TO FOUR O
ONE O TO TWO SI

55
Q

what are fullerenes?

A

. allotropes of carbon in form of hollow spheres or tubes
. structure of many is based on rings of carbon atoms, like graphite, in hexagons and sometimes pentagons
. properties unlike graphite
. dimensions between 0.1 and 100 nanometers
ONE C TO THREE C

56
Q

what is buckminsterfullerene?

A

. simple molecular structure of carbon
. formula C60
. shape of football
. C atoms arranged at corners at ends of 20 hexagons and 12 pentagons
. bonds between two hexagons are shorter than those between hexagons and pentagons
. has some delocalised electrons but less than graphite

57
Q

what is buckminsterfullerene?

A

. simple molecular structure of carbon
. formula C60
. shape of football
. C atoms arranged at corners at ends of 20 hexagons and 12 pentagons
. bonds between two hexagons are shorter than those between hexagons and pentagons
. has some delocalised electrons but less than graphite

58
Q

properties of buckminsterfullerene?

A

. low sublimation point - weak intermolecular forces
. soft - not much energy required to overcome weak intermolecular forces
. poor conductor of electricity - extent of electron delocalisation is lower
. slightly soluble in solvents, unlike graphite and diamond
. more reactive than graphite or diamond - bucky reacts with H, Cl, F, Br, O, due to relatively high electron density

59
Q

what is a nanotube?

A

fullerene of hexagonally arranged carbon atoms like a single layer of graphite bent into the form of a cylinder

60
Q

nanotube size

A

small diameter, long length

61
Q

properties of nanotubes?

A

. have high electrical conductivity - have delocalised electrons
. high tensile strength - 100 times stronger than steel
. very high melting points - strong covalent bonding

62
Q

uses of fullerenes

A

. buckminsterfullerene - trap small molecules in its cages, deliver drugs to certain parts of the body
. nanotubes - as wires in tiny electrical circuits, electrons in thin batteries, treating types of cancer, clothing for added strength

63
Q

what is graphene?

A

single isolated layer of graphite, layer is not entirely rigid and can be distorted

64
Q

graphene properties

A

. most chemically reactive form of carbon
. single sheets of graphene burn at very low temperatures, much more reative than graphite
. extremely strong for its mass
. conducts electricity and heat better than graphite

65
Q

graphene uses

A

. uses in tiny electrical circuits
. for tiny transistors
. tiny touchscreen
. tiny solar cells
. tiny energy storages devices