05 - states of matter Flashcards
gas particles are:
. far apart (so can be compressed)
. are randomly arranged
. can move freely from place to place, in all directions
liquid particles are:
. close together (so have a fixed volume, can only be compressed slightly)
. mostly randomly arranged
. limited movement from place to place
LIQUIDS TAKE THE SHAPE OF THE CONTAINER
solid particles are:
. touching each other (can’t be compressed)
. usually in a regular arrangement
. can’t change positions with each other, only vibrate
SOLIDS HAVE A FIXED SHAPE AND VOLUME
what are the types of structures found in elements and compounds:
. simple molecular/simple atomic
. giant ionic
. giant metallic
. giant molecular (noble gases thought of having this structure, although they exist as isolated atoms)
what is the kinetic theory of gases?
. the theory that particles in gases liquids are in constant movement
. used to explain the effect of temperature and pressure on the volume of a gas as well as the rates of chemical reactions
what are the assumptions made by the kinetic theory of gases?
. gas molecules move rapidly and randomly
. dist. betwesn gas molecules»_space;> diameter of molecules SO they have nelegible volume
. no intermolecular forces of attraction or repulsion between the molecules
. collisions between particles are elastic (no kinetic energy lost in collisions)
. temperature of the gas is related to avg. ke of the molecules
what is an ideal gas?
a gas whose volume varies in proportion to the temperature and in inverse proportion to the pressure
noble gas approach ideal gas behavior (due to their low intermolecular forces)
what is a real gas?
a gas that does not obey the ideal gas law, especially at low temps and high pressures
volume of a gas depends on:
. pressure in Pa
. temperature in K
volume relation to pressure?
volume = 1/pressure
volume relation to temperature?
volume is directly proportional to temp
in what ways do real gases not ovbey the kinetic theory?
. not zero attraction between molecules
. volume of molecules are not neligible
under high pressure and low temp, real gases:
. molecules are close to each other
. volume of the molecules not negligible
. there are id id or pd pd forces between molecules
. attractive forces pull mols towards each toher and away from container
. pressure lower than expected
. effective volume of gas is smaller than ideal gas
whats the formula?
pV=nRT
pV=nRT stands for?
p = pressure in Pa
V = colume of gas in cm3
n = no. of moles of gas
R = gas constant (8.31 J K-1 mol-1)
T = temperature in K
celsius to kelvin
+ 273
methods of calculating relative molecular mass?
. use a mass spectrometer, accurate
. use general gas eq, less accurate
melting for solids?
. energy transferred makes particles vibrate more vigorously
. forces of attraction between particles weaken
. solid beocmes liquid at its melting point
what is the melting point of a solid?
the temperature at which it changes to a liquid at 1atm
to melt ionic compounds, need…
high temp (strong bonds)
to melt molecular solids, need…
low temperature (weak intermolecular forces between particles)
what is vaporisation?
the change in state when a liquid changes to vapour
when heating a liquid?
. particles move faster
. forces for atrraction between particles weaken
. particles with most energy escape first
. liquid evaporates (at temp below boiling point)
. forces weaken for all the particles to become completely free from each other
. liquid boils at boiling point
what enthalpy change of vaporisation?
the energy required to change one mole of liquid to one mole of gas
what is condensation?
the change in state when a vapour change to a liquid
are chnages in states reversible?
YES