Valence Bond Theory Flashcards
VB theory Treats the formation of a molecule as arising from
The bringing together of complete atoms which retain most of their structure upon interacting
VB theory Considers the reactions between
Separate atoms as they are brought together to form molecules
VB theory Works on the premise that
Electrons are paired whenever possible
VB theory is Unable to predict
Observed paramagnetism
VB theory Completely neglects
Excited states
VB theory is good for
Coordination compounds and simple molecules
What can contribute to a bond according to VB
Only paired electrons
How to ID a sigma bond
Rotate the bond around internuclear axis. Unchanged makes it a sigma
How to ID a pi bond
Rotate bond 180° around axis. If signs of lobes change then it’s a pi bond
VB theory says Hybrid orbitals form when
Atomic orbitals on the same atom interfere/mix