3D Bioinorganic

Question 1

Catalytic oxidation requires

Answer 1

Vacancy and redox activity

Question 2

Oxygen transport requires

Answer 2

Vacancy at central atom

Question 3

Does catalysis of non redox reaction require redox activity

Answer 3

No

Question 4

Does electron transfer require vacancy

Answer 4

No

Question 5

Electron transfer requires

Answer 5

Redox activity

Question 6

Inner sphere

Answer 6

Electron transfer between covalently connected metals

Question 7

Outer sphere

Answer 7

Electron transfer through space

Question 8

Physical properties that are size dependent

Answer 8

Color, magnetism, melting point

Question 9

Transmission electron microscopy (TEM)

Answer 9

Precise shape, desolvated size as solid

Question 10

Dynamic light scattering (DLS)

Answer 10

No shape (approximation for spheres), investigation in solution (solvated)

Question 11

role of V

Answer 11

enzymes

Question 12

role of Cr

Answer 12

glucose metabolism

Question 13

role of Mn

Answer 13

enzymes and photoredox

Question 14

role of Fe

Answer 14

electron transfer systems, oxygen storage and transport, iron storage, iron transport proteins, enzymes

Question 15

Role of Co

Answer 15

vitamin b12 enzyme

Question 16

role of Ni

Answer 16

enzymes

Question 17

Role of Cu

Answer 17

electron transfer, oxygen storage and transport, Cu transport proteins

Question 18

role of Zn

Answer 18

lewis acid, structure

Question 19

role of Mo

Answer 19

enzymes