HW Reviews Flashcards

1
Q

What is the relationship between 2H and 1H?

A

isotopes

Isotopes are variants of a particular chemical element that have the same number of protons but different numbers of neutrons.

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2
Q

What is the relationship between 40Ca and 115Cd?

A

none

These two elements do not share a relationship in terms of isotopes, isobars, or isotones.

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3
Q

What is the relationship between 40Ar, 40K, and 40Ca?

A

isobars

Isobars are nuclides that have the same mass number but different atomic numbers.

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4
Q

What is the relationship between 56Fe and 57Co?

A

isotones

Isotones are nuclides that have the same number of neutrons but different numbers of protons.

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5
Q

What is the relationship between 12C and 14C?

A

isotopes

Both 12C and 14C are carbon isotopes, differing in the number of neutrons.

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6
Q

Can pure Si act as an intrinsic semiconductor?

A

Yes

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7
Q

What effect does doping with phosphorous have on the band structure of silicon?

A

Adds valence electron
* Adds another energy level below conduction band (creates donor level)
* Becomes n-type

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8
Q

What effect does doping with boron have on the band structure of silicon?

A

Boron has less valence electrons
* Adds holes above energy levels of valence band (creates acceptor level)
* Becomes p-type

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9
Q

What is the name of the effect utilized in solar cells to excite valence electrons to the conducting band?

A

Photovoltaic effect

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10
Q

What coordination geometry do you expect for [Pd(PPh3)4]?

A

tetrahedral

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11
Q

Which is paramagnetic: square Planar or tetrahedral

A

tetrahedral because weaker splitting by Ligands being further apart increasing unpaired electrons

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12
Q

What coordination geometry do you expect for [Mn(OH2)6]2+?

A

octahedral

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13
Q

Is [Mn(OH2)6]2+ a high-spin complex?

A

yes

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14
Q

Why is Si an intrinsic semiconductor

A

4 VE for 4 Bonds means no holes

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15
Q

Is square planar usually high or low spin

A

Low spin

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16
Q

Use Bells rule to explain why pKa values could be similar

A

pKa is related to energy req to remove a proton
More oxygen means lower pKa
More easily removed H means lower pKa
Element having more O is comparable to element more willing to release H

17
Q

de Broglie’s wave equation

A

wavelength = h/mv

18
Q

K shell =

A

1

19
Q

N shell =

A

4

20
Q

Hydrogen combustion

A

H2O: an oxide

21
Q

Sodium Combustion

A

Na2O2: peroxide

22
Q

Magnesium combustion

A

MgO: oxide

23
Q

Cesium combistion

A

CsO2: superoxide

24
Q

Barium combistion

A

BaO2: peroxide

25
Q

which bond is stronger: superoxide or peroxide

A

superoxide

26
Q

lower bond order

A

weaker bond

27
Q

higher bond order

A

stronger bond

28
Q

has unpaired electrons

A

paramagnetic

29
Q

no unpaired electrons

A

diamagnetic

30
Q

according to pauling electronegativity, these elements break the usual trend

A

Si and Al are lower than atoms below them