Unit 3: Energy and Living Systems Flashcards
metabolism
the totality of an organism’s chemical reactions
-as a whole, manages the material and energy resources of the cell
metabolic pathway
begins with a specific molecule which is then altered in a series of defined steps (enzyme catalyzed reactions) resulting in a certain product
catabolic pathways
metabolic pathways that release energy by breaking down complex molecules to simpler compounds
-ex. cellular respiration
anabolic pathways
consume energy to build complicated molecules from simpler ones
-ex. synthesis of amino acids and proteins
bioenergetics
study of how energy flows through living systems
energy
the capacity to cause change or rearrange a collection of matter
kinetic energy
energy associated with the relative motion of objects
thermal energy
kinetic energy associated with the random movements of atoms or molecules
potential energy
energy matter possesses because of its location
chemical energy
refers to the potential energy available for release in a chemical reaction
thermodynamics
the study of energy transformations that occur in a collection of matter
First Law of Thermodynamics
- energy can be transferred and transformed but it cannot be created or destroyed
- during every transfer or transformation some energy becomes unavailable to do work (lost as heat)
entropy
- a measure of disorder
- increased by a loss of usable energy (heat given off)
- sometimes visible as a physical disintegration of a structure
Second Law of Thermodynamics
every energy transfer or transformation increases the entropy of the universe
spontaneous process
a process that can occur without an input of energy
-must increase entropy of universe to occur
Free energy
the portion of a system’s energy that can perform work when temp and pressure are uniform throughout the system
-can be seen as a measure of a system’s instability (tendency to change to a more stable state)
Free energy change, ^G
^G= ^H-T^S ^H= change in enthalpy ^S= change in systems entropy T= absolute temperature (K) -only processes with negative ^G are spontaneous (spontaneous process decrease system's free energy)
chemical equilibrium
when forward and backwards reaction occur at the same rate
Free Energy and Euilibrium
free energy decreases, as a reaction proceeds toward equilibrium
- a reaction in equilibrium cannot perform work
- a process is spontaneous and can perform work only when it is moving toward equilibrium
Exergonic reaction
negative change in G
- proceeds with a net release of free energy
- reactions that occur spontaneously
- ^G = maximum amount of work a reaction can perform
Endergonic reaction
- absorbs free energy from surrounding (+^G)
- non-spontaneous
- ^G= energy required to drive the reaction
Equilibrium and Metabolism
- reactions in an isolated system will eventually reach equilibrium
- constant flow of material into and out of a cell keeps metabolic pathways from reaching equilibrium
- product of one reaction becomes a reactant in the next step (occurs in cellular respiration)
Cell does 3 kinds of work
- chemical work: pushing of endorgonic reactions that would not occur spontaneously
- transport work: actively pumping substances across membrane
- mechanical work: cell movement
energy coupling
use of an exergonic process to drive a endergonic one