Types of Organic Reactions + Reaction Mechanisms : Bond Breaking and Bond Formation (Part 1) Flashcards

1
Q

what is a substitution ?

A

is a reaction in which an atom or a group of atoms is replaced by another atom or group of atoms.

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2
Q

Which bonds are involved in susbtitution ?

A

sigma ()bonds: one  bond breaks and another one forms at the same carbon atom.

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3
Q

what is the most coomon substitution ?

A

when Z is a hydrogen or a heteroatom that is more electronegative than carbon.

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4
Q

Common examples of substitution

A

substitution are reactions involving alcohols or haloalkanes

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4
Q

Common examples of substitution

A

substitution are reactions involving alcohols or haloalkanes

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5
Q

what is an addition reaction ?

A

a reaction in which two molecules add together to form a single product

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6
Q

what are addition reaction a characteristic of ?

A

unsaturated compounds with multiple bonds such as alkenes, alkynes and carbonyl compounds

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7
Q

what are elimination reactions ?

A

involves a reaction in which a simple molecule splits off from within a larger molecule to form a double bond.

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7
Q

what are elimination reactions ?

A

involves a reaction in which a simple molecule splits off from within a larger molecule to form a double bond.

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8
Q

most common examples of elimination

A

when X = H and Y is a heteroatom more electronegative than carbon.

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9
Q

most common examples of elimination

A

when X = H and Y is a heteroatom more electronegative than carbon.

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10
Q

what is the force for an elimination reaction ?

A

the formation of a small, stable molecule

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11
Q

what is a reaction mechanism ?

A

a detailed description of how bonds are broken and formed as starting material is converted into product.

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11
Q

what is a reaction mechanism ?

A

a detailed description of how bonds are broken and formed as starting material is converted into product.

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12
Q

what are the 2 reactive intermidiates ?

A

ions or radicals

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13
Q

how are the electrons in Homolytic Bonds ?

A

the electrons are divided equally between the atoms in the bond that breaks.

14
Q

what is a free radical ?

A
  • A reactive intermediate with a single unpaired electron
  • highly unstable as they contain an atom that does not have an octet of electrons.
14
Q

what is a free radical ?

A
  • A reactive intermediate with a single unpaired electron
  • highly unstable as they contain an atom that does not have an octet of electrons.
15
Q

how are the electrons in heterolytic ?

A

the electrons are divided unequally between the atoms in the bond that breaks.

15
Q

how are the electrons in heterolytic ?

A

the electrons are divided unequally between the atoms in the bond that breaks.

16
Q

type of bonsding in heterolytic bonding ?

A

ionic intermediates