Reactions of alkanes, Halogenation, Reaction conditions, Free radical reaction mechanism,Curly arrows,The chlorination of ethane Flashcards

1
Q

Reactions of Alkanes

A
  1. Combustion
    reaction with oxygen
  2. Halogenation
    - alkanes react with bromine, chloride to form haloalkanes
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2
Q

Reaction Conditions

A
  • Heat or light
    Homolytically breaks the covalent Cl-Cl bond to produce free radicals

Homolytic bond breaking:
When the bond breaks, each atom leaves with one electron

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3
Q

Free Radical Reaction Mechanism 1

A

Initiation:
● producing reactive free radicals

Propagation:
* produces product, and more free radicals
1. radicals collide with alkane, and abstract H
2. radical chain reaction repeats in an endless cycle

Termination:
* two radicals combine to form a stable molecule, and the reaction cycle is ended

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4
Q

Curly Arrows
what does th head show ?
wjhat does the tail show ?

A

head:
* points to where electrons are going
- single: movement of one electron
- double: movement of electron pair

tail:
* shows where electrons have come from

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