Structural Isomer & Geometric Isomers Flashcards

1
Q

What are isomers divided into ?

2 types

A
  • Structural Isomers
  • Stereoisomers
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2
Q

what are isomers ?

A

different compounds with same molecula formula

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3
Q

what are structural isomers ?

A

isomers whose atoms have different connectivity

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4
Q

what are stereoisomers ?

A

isomers that have the same connectivity but differ in spatial arrangement of their atoms

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5
Q

what are stereoiomers divided into ?

2 types

A
  • Optical isomers
  • Geometric isomers
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6
Q

what are optical isomers ?

A

stereoisomers that are non-superimposable mirror images of each other

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7
Q

what are geometric isomers ?

A

stereoiosmers that occur due to restricted rotation

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8
Q

what are the 3 types of structural isomers ?

A
  1. Chain Isomers
  2. Positional Isomers
  3. Functional Group Isomers
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8
Q

what are the 3 types of structural isomers ?

A
  1. Chain Isomers
  2. Positional Isomers
  3. Functional Group Isomers
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9
Q

what are chain isomers ?

A
  • These type of isomers tend to have similar chemical properties and slightly different physical properties
  • These isomers arise due to different arrangements of the carbon skeleton in the molecules.
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10
Q

what are positionla isomers ?

A
  • These isomers have same carbon skeleton and same functional group, but the functional group is in a diffrent postion
  • The isomers tend to have similar chemicla properties and slightly diffrent physical properties
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10
Q

what are positionla isomers ?

A
  • These isomers have same carbon skeleton and same functional group, but the functional group is in a diffrent postion
  • The isomers tend to have similar chemicla properties and slightly diffrent physical properties
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11
Q

what are functionla group isomers ?

A
  • The isomaers have the same molecular formula and carbon skeleton, but different functional groups
  • This type of isomers tend to have different chemical properties and different physical properties
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11
Q

what are functionla group isomers ?

A
  • The isomaers have the same molecular formula and carbon skeleton, but different functional groups
  • This type of isomers tend to have different chemical properties and different physical properties
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12
Q

what are the most common types of geometric isomers ?

A

Alkenes and Cyclic Compounds

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13
Q

what are geometric isomers sometimes referred as ?

A

cis-trans

13
Q

what are geometric isomers sometimes referred as ?

A

cis-trans

14
Q

what is a cis isomer ?

A

when similar functional groups are on same sides of the double bond

15
Q

what is a trans isomer ?

A

When similar functional groups are on the opposite side of the double bond

15
Q

what is a trans isomer ?

A

When similar functional groups are on the opposite side of the double bond

16
Q

what is E/Z Convention?

A

a systematic system to differentiate between geometric isomers

16
Q

what is E/Z Convention?

A

a systematic system to differentiate between geometric isomers

17
Q

what is an E configuration ?

A

when the highest priority groups are on the opposite side of the double

18
Q

what is a Z configuration ?

A

when the highest priority groups are on the same side of the double bond