TOPIC 13- ELECTROCHEMISTRY Flashcards

1
Q

is the study of the relationships between electricity
and chemical reactions
. It includes the study of both spontaneous and
nonspontaneous
processes.

A

Electrochemistry

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2
Q

is the loss of electrons. (oxidation number increases)

A

Oxidation

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3
Q

is the gain of electrons. (oxidation number decreases)

A

Reduction

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4
Q

The oxidizing agent is __________, and the reducing agent is _________.

A

reduced, oxidized

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5
Q

its purpose is to keep track of what loses electrons and what gains them

A

Oxidation Numbers

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6
Q

increase in oxidation numbers means

A

oxidized

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7
Q

decrease in oxidation numbers means

A

reduced

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8
Q

What are the electrochemical cells?

A
  1. Voltaic Cell
  2. Electrolytic Cell
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9
Q

Energy is released from a
spontaneous redox reaction and Work is done by the system on the load.

A

voltaic cell

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10
Q

Energy is absorbed from a
nonspontaneous redox reaction and work is done on the system by the load.

A

Electrolytic Cell

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11
Q

In a _________, the mass of the anode decreases over time as it turns
into ions, while the mass of the cathode increases.

A

voltaic cell

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12
Q

In voltaic cell, the electrical flow is always

A

from the anode to the cathode

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13
Q

In Electrolytic Cell, the electrical flow is

A

from the cathode to the anode

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14
Q

have values corresponding to reduction half-reactions with all solutes at 1 M and all gases at 1 atm.

A

Standard reaction potentials 𝐸𝑐𝑒𝑙𝑙

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15
Q

The more positive the value of the standard reduction potential, the greater the tendency for β€”β€”β€” under standard conditions.

A

reduction

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16
Q

have the most positive reduction potentials.

A

strongest oxidizers

17
Q

have the most negative reduction potentials.

A

strongest reducers

18
Q

The cell potentials of β€”β€”- are higher than those of the cathodes.

A

anode

19
Q

The cell potential in a voltaic cell is

A

always positive

20
Q

The increase and decrease of concentration is _____________ to cell
potential

A

directly proportional

21
Q

When the concentration of reactants is increased, both the electron driving
force and cell potential __________.

(products are favored, shifts right)

A

increases

22
Q

When the concentration of the products is increased, both the electron
driving force and cell potential —–.

(reactants are favored, shifts left)

A

decreases

23
Q

Both compartments of ___________
have the same components but at different
concentrations.

A

concentration cells

24
Q

is the only factor
that produces a cell potential.

A

Difference in concentration

25
Q

The electrons flow in the direction that tends
to

A

equalize the concentration

26
Q

Oxidation occurs on the

A

dilute solution

27
Q

gives the relationship between the cell potential and
the concentrations of the cell components.

A

nernst equation