TOPIC 10- ACIDS AND BASES Flashcards

1
Q

increase hydrogen (𝐻+ ) concentrations in an aqueous solution.

A

Acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

increases hydroxide (𝑂𝐻-) concentrations in an aqueous solution.

A

Bases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

are proton (𝐻+) donors.

A

Acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

are proton (𝐻+) acceptors.

A

Bases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

When 𝐻 receives a proton, it becomes

A

hydronium (H3O+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

If the acid is strong, use a

A

forward arrow

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

If the acid is weak, use a

A

double-headed arrow

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

is everything that remains of the acid molecule
after a proton is lost.

A

conjugate base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

is formed when the proton transfers to the base.

A

conjugate acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

consists of two substances related to
each other by the donating and accepting of a single proton.

A

conjugate acid-base pair

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

In strong acids, equilibrium lies far to the

A

right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

In strong acids, almost all the original HA is ____________________ at equilibrium

A

dissociated (ionized)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Strong acids, yields a

A

weak conjugate base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

an acid whose conjugate base is a much weaker base than water

A

Strong acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What are the 7 strong acids?

A

● 𝐻𝐢𝑙 (hydrochloric acid)
● 𝐻𝐼 (hydroiodic acid)
● π»π΅π‘Ÿ (hydrobromic acid)
● 𝐻𝑁𝑂 (nitric acid) 3
● 𝐻𝐢𝑙𝑂 (chloric acid) 3
● 𝐻𝐢𝑙𝑂 (perchloric acid) 4
● 𝐻 (sulfuric acid)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

In weak acids, equilibrium lies far to the

A

left

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

In weak acids, most of the acid placed is still present as __ at equilibrium

A

HA

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

has a conjugate base that is a much stronger base than water

A

Weak Acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

has a higher (𝐻3O+) and a larger Ka value.

A

stronger acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

has a lower (𝐻3O+) and a smaller Ka value.

A

weaker acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

can act as either an acid or base

A

amphoteric substance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

Example of amphoteric substance

A

water, 𝐻𝐢𝑂3- and
𝐻𝑃𝑂42-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

The [H3O+] and [OH-] are

A

inversely proportional

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

If [H3O+] > [OH-], the solution is

A

acidic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
If [H3O+] < [OH-], the solution is
basic
26
If [H3O+] = [OH-], the solution is
neutral
27
is the negative of the base-10 logarithm of a number.
p-scale
28
is the negative logarithm of [H3O+] or [OH-]
pH
29
As [H+] increases, the pH
decreases
30
The lower the pH and pKa, the __________ the acid
stronger
31
The extent of ionization of a weak acid can be described in terms of the
degree of ionization or percent ionization.
32
is the fraction of the ionized acid molecules.
degree of ionization
33
gives the percentage of ionized molecules.
percent ionization
34
When you dilute a solution, the percent ionization
increases
35
If the base is strong, use a
forward arrow
36
If the base is weak, use a
double-headed arrow.
37
completely dissociate when dissolved in an aqueous solution
strong bases
38
strong bases include hydroxides of
Group 1A and 2A elements
39
have larger 𝐾 values
strong bases
40
partially dissociate when dissolved in an aqueous solution and exists in a solution as mixture of itself and its conjugate acid
Weak Bases
41
have smaller 𝐾 values
Weak Bases
42
will lie to where the weaker acids and bases are found.
equilibrium of acid-base reaction
43
If equilibrium lies to the right, 𝐾a is
large (strong)
44
If equilibrium lies to the left, 𝐾a is
small (weak)
45
The equilibrium concentration of a strong acid/base is always
zero
46
If 𝐾w increases as temperature increases, the process is
endothermic
47
𝐾a and Kb are ____________________ to each other.
inversely proportional
48
The sum of pH and pOH is always
14.00
49
have a pH greater than 7.00.
Bases
50
have a pH less than 7.00.
acids
51
The lower the 𝑝𝐾 , the ___________ the acid
stronger
52
The pH of pure water will always be______regardless of temperature.
7.00
53
is the shift in equilibrium caused by the addition of a compound having an ion in common with the dissolved substance.
common ion effect
54
The presence of a ______________ suppresses the ionization of a weak acid or a weak base.
common ion
55
is one that resists a change in its pH when either hydroxide ions or protons are added.
buffered solution
56
most important practical example of a buffered solution is our _______, absorbing acids/bases in biological reactions without changing its pH.
blood
57
is a combination of a weak acid/base and a salt of that weak acid/base.
buffered solution
58
________ acids and bases cannot form buffer solutions.
Strong
59
of a buffered solution represents the amount of protons or hydroxide ions the buffer can absorb without a significant change in pH.
buffering capacity
60
The more concentrated the components of a buffer, the _______ the buffer capacity.
greater
61
A buffer has the highest capacity when the component concentrations are
equal
62
The most efficient buffering occurs when the [A]/[HA] ratio is close to
1
63
is the pH range over which the buffer acts effectively.
Buffer range
64
Steps in Preparing Buffer Solutions
1. Choose the conjugate acid-base pair. 2. Calculate the ratio of buffer component concentrations. 3. Determine the buffer concentration. 4. Mix the solution and adjust the pH.