Thermodynamics Flashcards

1
Q

what is the formula & definition of change in energy

A

the sum of all the energy components in the system

for thermodynamics

change in E = q + w
where E is the sum of kinetic & potential energies (only kinetic for gas), q is the heat transferred & w is the work done

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2
Q

what is q for endothermic

A

+ve

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3
Q

what is q for exothermic

A

-ve

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4
Q

what is w if the system does work on the surroundings

A

-ve

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5
Q

what is w if the system gets work done to it

A

+ve

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6
Q

what is enthalpy

A

heat transferred at constant pressure (-ve)

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7
Q

what is the formula for change in enthalpy

A

change in E or E of products - E of reactants

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8
Q

what does it mean if the enthalpy is endothermic

A

less energy goes to reactants and products have higher potential energy

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9
Q

what is heat capacity

A

energy required to raise the temp of the object by 1C or 1K

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10
Q

what is specific heat capacity

A

energy for one gram

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11
Q

what is molar heat capacity

A

energy for one mole

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12
Q

what is a calorimeter

A

a device used to measure heat flow

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13
Q

in thermodynamics, what can the change in enthalpy be approximated to

A

change in energy

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14
Q

what is the melting point of ice

A

0deg. C

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15
Q

given the equlibrium constants of 2 reactions, how do you determine the constant if the reactions are added together

A

Kc1*Kc2

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16
Q

what is dalton’s law on partial pressure

A

(assuming equilibrium)
total partial pressure = sum of individual partial pressures

17
Q

what does an increase in entropy mean

A

an increase in the number of microstates, disorder & dispersal

18
Q

what happens to entropy if the number of moles increases

A

entropy increases

19
Q

what happens to entropy when the volume is increased

A

entropy increases

20
Q

what happens to entropy when temperature increases

A

entropy increases

21
Q

are gasses more disorderd (more microstates) than liquids

A

yes