Thermodynamics Flashcards

1
Q

Define enthalpy of formation

A

The enthalpy change when one mole of a compound if formed from its constituent elements under standard conditions with all reactants and products under standard states

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2
Q

Define first ionisation energy

A

The enthalpy change required to remove one mole of electrons from one mole of a gaseous atoms to form one mole of gaseous ions with a one plus charge

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3
Q

Define enthalpy of atomisation

A

The enthalpy change when one mole of gaseous atoms are formed from the elements in their standard states

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4
Q

Define bond enthalpy

A

Energy required to break a covalent bond in 1 mole of gaseous ions

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5
Q

Define electron affinity

A

The enthalpy change when 1 mole of gaseous ions atoms gains 1 mole of electrons to form 1 mole of gaseous ions with -1 charge

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6
Q

What are born Haber cycles used for ?

A

To calculate lattice enthalpies.

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7
Q

Define the term enthalpy of hydration

A

The enthalpy change when one mole of gaseous ions become aqueous ions

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8
Q

What is the general equation to work out the lattice enthalpy of formation?

A
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9
Q

Define entropy

A

The measure of disorder

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10
Q

What is the Gibbs free equation?

A
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11
Q

What does the Gibbs free equation determine?

A
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12
Q

For a reaction to be feasible, what must the value of deltaG be?

A
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13
Q

What factors affect disorder?

A
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14
Q

What does “the perfect ionic model” mean?

A
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15
Q

How does covalent character form?

A
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16
Q

How does covalent character affect lattice enthalpy?

A
17
Q

List the factors affecting lattice enthalpy of formation

A