1
Q
mechanism order
A
- make protecting group and protect OH
- do other chemistry
- remove protecting group
2
Q
how to make the protecting group
A
t-buOH + H+ makes Sn1 carbocation that ROH attacks (H2O deprotonates)
3
Q
how to deprotect
A
dilute H3O+
Organic Chemistry II
flashcards
Decks in class (56)
# Cards
-
Alcohol Nomenclature5
-
Properties of Alcohols11
-
Synthesis of Alcohols15
-
Grignard11
-
Organolithium3
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Oxidation of Alcohols11
-
PBr3 & PCl37
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SOCl26
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Sulfonates6
-
Properties of Ethers5
-
Ether Formation2
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Williamson Ether Synthesis6
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Bimolecular Dehydration (-H2O)7
-
Alcoholysis5
-
Acidic Ether Cleavage5
-
t-butyl alcohol protection3
-
Silyl Ether Protection4
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Base Catalyzed Epoxide Opening3
-
Acid Catalyzed Epoxide Opening4
-
Alkene Properties10
-
E/Z Nomenclature4
-
Zaitsev vs. Hofmann2
-
Dehydration of Alcohol6
-
Post-Exam 20
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Hydrohalogenation7
-
Radical Hydrobromination5
-
Hydration3
-
Acid-Catalyzed Hydration8
-
Oxymercuration-Demercuration9
-
Hydroboration/Oxidation7
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Halogenation8
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Carbenes + Addition of Carbenes3
-
Carbene Formation5
-
Epoxidation4
-
Hydroxylation6
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Oxidative Cleavage5
-
Conjugated Dienes10
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Alkynes and Their Properties11
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Alkylation5
-
Dehydrohalogenation11
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Alkyne Catalytic Hydrogenation5
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Alkyne Halogenation4
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Alkyne Hydrohalogenation5
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Hydration of Alkynes6
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Keto Enol Tautomerization4
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Heck Rxn4
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Acid Chlorides3
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Gilman4
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DIBAL3
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Acetals4
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Wittig Rxn5
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Enols and Enolates3
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Aldol and Retro-Aldol4
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Alkylation With Enolate2
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Michael Addition1
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1,2 and 1,4 addition again4
