Oxidative Cleavage Flashcards by Molly Gallagher | Brainscape

Q

purpose

A

make aldehydes & ketones from carbonyl

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Q

2 methods

A

O3 (ozone)

KMnO4 gone wrong

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Q

O3 method

A

1 step

O3, CH2Cl2, -78ºC,

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Q

hydroxylation gone wrong method

A

1 step

KMnO4, warm, NaOH (conc)

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Q

hydroxylation gone wrong IMPORTANT

A

will overoxidize aldehydes to carbox acids.

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