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Organic Chemistry II

This class was created by Brainscape user Molly Gallagher. Visit their profile to learn more about the creator.

Decks in this class (56)

Alcohol Nomenclature
Alkane,
How to,
If more than 1 oh group
5  cards
Properties of Alcohols
H bonding,
Type of bond,
Amphoteric
11  cards
Synthesis of Alcohols
Oxidation reduction memory aid,
Oxidation definition,
Reduction definition
15  cards
Grignard
Organometallic reagents,
To make grignard reagents,
Best halides for grignards
11  cards
Organolithium
Speed vs grignard,
General rxn,
Rxn conditions
3  cards
Oxidation of Alcohols
Oxidation definition,
In general what alcohols turn int...,
Chromium reagents
11  cards
PBr3 & PCl3
Purpose pbr3,
Best substrates for pbr3,
Mechanism of pbr3
7  cards
SOCl2
Purpose,
Does hcl form,
Best substrates
6  cards
Sulfonates
Purpose,
Names of sulfonates we ve learned,
When you add the lg to the roh wh...
6  cards
Properties of Ethers
Is there h bonding,
Bp mp vs alcohol,
Acidic proton
5  cards
Ether Formation
How many ways to make an ether,
Which ways are capable of intramo...
2  cards
Williamson Ether Synthesis
Purpose,
Requires,
R x limitations
6  cards
Bimolecular Dehydration (-H2O)
Purpose,
Requires,
Best alcohol substrate
7  cards
Alcoholysis
Purpose,
Best substrates,
Mechanism
5  cards
Acidic Ether Cleavage
Purpose,
Need,
Best substrate
5  cards
t-butyl alcohol protection
Mechanism order,
How to make the protecting group,
How to deprotect
3  cards
Silyl Ether Protection
Name of molecule,
Does this rxn make hcl,
How to remove protecting group
4  cards
Base Catalyzed Epoxide Opening
Attacks which side,
Types of nu,
Product
3  cards
Acid Catalyzed Epoxide Opening
Attacks which side,
Hx product,
Type of addition
4  cards
Alkene Properties
Structure bonding,
Sp2 hybridized planar bond angle,
Info about pi bond
10  cards
E/Z Nomenclature
E stands for,
Z stands for,
When do we use e z
4  cards
Zaitsev vs. Hofmann
Zaitsev product,
Hofmann product
2  cards
Dehydration of Alcohol
Purpose,
Need,
1
6  cards
Post-Exam 2
0  cards
Hydrohalogenation
Purpose,
X,
Syn or anti
7  cards
Radical Hydrobromination
Purpose,
Need,
Type of mechanism
5  cards
Hydration
Purpose,
2 modes,
Types 1 direct 2 indirect
3  cards
Acid-Catalyzed Hydration
Mode,
Purpose,
Need
8  cards
Oxymercuration-Demercuration
Mode,
Purpose,
Mercuric acetate
9  cards
Hydroboration/Oxidation
Mode,
Purpose,
Markovnikov or anti
7  cards
Halogenation
Purpose,
Need,
Solvent
8  cards
Carbenes + Addition of Carbenes
What is a carbene,
Hybridization and val e,
Addition of carbene to alkene
3  cards
Carbene Formation
3 ways,
Diazomethane,
Make simmons smith reagent
5  cards
Epoxidation
What is peroxy acid,
Mcpba,
Overall rxn
4  cards
Hydroxylation
Purpose,
2 types of reagent,
Oso4
6  cards
Oxidative Cleavage
Purpose,
2 methods,
O3 method
5  cards
Conjugated Dienes
Preparation,
2 theories of stability,
Hybridization
10  cards
Alkynes and Their Properties
Hybridization and bond angle,
Terminal alkyne stability,
Internal alkyne stability
11  cards
Alkylation
Purpose,
3 ways,
Solvent used
5  cards
Dehydrohalogenation
Purpose,
Geminal definition,
Vicinal definition
11  cards
Alkyne Catalytic Hydrogenation
Purpose,
How to reduce to alkane,
How to reduce to a cis alkene
5  cards
Alkyne Halogenation
Purpose,
X,
How to make a dihaloalkene
4  cards
Alkyne Hydrohalogenation
Purpose,
X,
If starting with a terminal alkyne
5  cards
Hydration of Alkynes
Purpose,
To form a ketone only,
To form an aldehyde ketone
6  cards
Keto Enol Tautomerization
What is a enol,
Tautomers,
Enol under acidic conditions mech...
4  cards
Heck Rxn
Purpose,
What is needed,
What happens
4  cards
Acid Chlorides
How to make,
Carbox acid to aldehyde,
Other acid chloride rxn nucleophiles
3  cards
Gilman
Purpose,
Reagent,
Compatible fg
4  cards
DIBAL
Purpose,
Reagent,
Rxn conditions
3  cards
Acetals
What is an acetal,
How to form,
Real life example
4  cards
Wittig Rxn
Purpose,
Process,
Alkyl halide restrictions
5  cards
Enols and Enolates
If multiple alpha hydrogens,
More stable product,
Less stable product
3  cards
Aldol and Retro-Aldol
Aldol condensation purpose,
What is needed for aldol condensa...,
Driving force of aldol condensation
4  cards
Alkylation With Enolate
What is needed,
What is special about this
2  cards
Michael Addition
Mechanism
1  cards
1,2 and 1,4 addition again
Conjugated systems have _ sites f...,
When does 1 4 addition happen,
When does 1 2 addition happen
4  cards

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