ST1&2 Flashcards
oxidizers
not combustible but support or enhance combustion
common:
calcium hypochlorite
chlorine
ammonium nitrate
hydrogen peroxide
methyl ethyl ketone
heat of combustion
potential energy available in combustion process
amount of energy required to change the temp of 1 gram of water by 1 degree C
4.2 joules
British thermal unit (Btu)
amount of heat required to raise 1 gallon of water 1 degree F
exothermic reaction
fire is exothermic that releases heat and sometimes light
endothermic reaction
absorbs energy
water to steam
fire must be in a gaseous state to occur
fire is gas phase combustion
off gassing in solids and liquids
pyrolysis
vaporization
piloted ignition
most common form of ignition
mixture of fuel and oxygen encounter outside heat source
autoignition
no source of flame or spark
fuels surface heats up enough
complete combustion of methane
produces heat, light, water vapor and Co2
CO
comes from carbon based organic materials
odorless, colorless and flammable
produced where there is limited O2 supply
chemical asphyxiant combines with hemoglobin 200 times more efficiently than O2
HCN
combustion of materials containing nitrogen and carbon
natural fibers(will, cotton, silk)
resins (carbon fiber, fiberglass)
synthetic polymers (nylon, polyester)
synthetic rubber (neoprene, silicone, latex)
polyeruthene foam
35 times more toxic than CO
prevents body from using O2 at cellular level
targets heart and brain
CO2
product of complete combustion
increases respiratory rate
displaces O2
common products of combustion
CO
formaldheyde
HCN
nitrogen dioxide
particulates
sulfur dioxide
convective flow
heated gases flow up and out, cooler clean air flows in
temperature
if you can go in
measurement of heat
measurement of the average kinetic energy in the particles of a sample of matter
not an accurate predictor of heat transfer
heat transfer
how long you can stay in
energy flow to a unit area (heat flux) measured in KW per sq meter
sources of thermal energy
chemical (most common) electrical and mechanical
types of electrical heating
resistance heating- space heater
overcurrent or overload-unintended resistance heating
arcing
sparking
mechanical energy
friction or compression
movement of two surfaces against each other
when a gas is compressed
heat transfer
transfer of heat from one point or object to another is part of the study of thermodynamics
conduction
transfer of heat between solids through direct contact
convection
transfer of thermal energy by circulation or movement of a fluid (liquid or gas)
radiation
transmission of energy as electromagnetic waves such as light waves, radio waves, or X-rays without and intervening medium.
can become dominant mode of heat transfer as fire grows
fuel
known as reducing agent
inorganic fuels
hydrogen
magnesium
organic fuels
most fuels are organic containing carbon
organic fuels divided into hydrocarbon based fuels
gasoline
fuel oil
plastics
cellulose based materials (wood and paper)
fuels heat of combustion
total amount of thermal energy released when a specific amount of fuel burns