Shapes Of Molecules and Intermolecular Forces Flashcards

1
Q

What does the arrangement of electron pairs do?

A

Minimises repulsion and holds the bonded atoms in a definitive shape

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2
Q

What causes different shapes?

A

Different numbers of electron pairs

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3
Q

What shape is it if there are four electron powers?

A

Tetrahedral

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4
Q

What is the bond angle in a tetrahedral shape?

A

109.5degress

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5
Q

Why is a lone pair more stronger repelling than a bonded pair of electrons?

A

A lone pair of electrons is slightly closer to the central atom and occupies more space

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6
Q

What shape is the molecule if there are 3 bonded pairs and one lone pair?

A

Pyramidal

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7
Q

What is the bond angle of a pyramidal molecule?

A

107degress

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8
Q

What is the shape of a water molecule?

A

Bent linear

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9
Q

What is the bond angle in a non linear shape? (Bent linear)

A

104.5degrees

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10
Q

What makes the bond angle smaller?

A

More electron pairs

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11
Q

What angle does a trigonal planar molecule have?

A

120 degrees

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12
Q

What bond angle does an octahedral molecule have?

A

90 degrees

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13
Q

What is electronegativity?

A

The attraction of a bonded atom for the pair of electrons in a covalent bond

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14
Q

What scale measures electronegativity?

A

The Pauling scale

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15
Q

What happens as you go right across the periodic table?

A

The electronegativity increases

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16
Q

What happens as you travel up the periodic table

A

The electronegativity increase

17
Q

What happens in a covalent molecule if there is a difference in electronegativity?

A

The covalent bond is pulled closer to the atom with more electronegativity

18
Q

Describe an ionic bond in terms of electronegativity

A

Large electronegativity difference
One atom has more of an attraction to the shared pair
More electronegative atom gained control of electrons

19
Q

What determine the shape of the molecule?

A

The electron pairs surrounding a central atom

20
Q

What is a non polar bond?

A

Where the bonded electron pair is shared equally between the bonded atoms

21
Q

When will there be a non polar bond?

A

When the bonded atoms are the same

The bonded atoms have the same or similar electronegativity

22
Q

What is a polar bond?

A

Where the bonded electron pair is shared unequally between the atoms

23
Q

What is a non polar bond also called?

A

A pure covalent bond

24
Q

Give an example of a polar molecule

25
What are intermolecular forces?
Weak interactions between dipoles of different molecules
26
What are the three types of intermolecular forces?
Induced dipole to dipole (ldf) Permanent dipole to dipole Hydrogen bonding
27
What are intermolecular forces responsible for?
Physical properties eg melting and boiling points
28
How is an induced dipole created?
The movement of electrons creates a changing dipole in a molecule Creating constantly shifting instantaneous dipole Which induces a dipole on its neighbour And so on
29
What happens to the ldf the more electrons are in a molecule?
Larger the instantaneous and induced dipole Greater induced dipole to dipole interactions Stronger attractive forces between molecules
30
Where do permanent dipoles happen?
Between the dipoles in polar molecules
31
Are simple molecular forces soluble in polar solvents?
No
32
Where is a hydrogen found between?
Molecules containing: An electronegative atom with a lone pair of electrons A hydrogen atom attached to an electronegative atom
33
What does the hydrogen bond act between?
The lone pair of electrons on me molecule and the hydrogen atom on the other molecule
34
What gives water it's weird properties?
The hydrogen bonding
35
Why is ice less dense than water?
Hydrogen bond holds water further apart in an open lattice structure with holes in it decreasing its density