S-block Elements Flashcards
Alkali Metals or Group-1 Metals
Lithium
Sodium
Potassium
Rubidium
Cesium
General electronic configuration of alkali metals
[ns]1
Atomic Radius Comparison of Alkali Metals
Li<Na<K<Rb<Cs<Fr
Difference in radius b/w element: Na-Li>Rb-K>Fr-Cs
Ionisation Energy Comparison of Alkali Metals
Li>Na>K>Rb>Cs>Fr
Ionic Radius Comparison of alkali metals
Li+<Na+<K+<Rb+<Cs+<Fr+
Melting and Boiling Point Comparison of Alkali Metals
It depends upon metallic bond strength.
Li>Na>K>Rb>Cs>Fr
Density Comparison of Alkali Metals
Li<Na<K<Rb<Cs<Fr
Flame colouration of alkali metals
Li: Carmine Red
Na: Golden Yellow
K: Lilac
Rb: Violet
Cs: Blue
How do alkali metals react with moist and dry air?
Lithium forms nitride and oxide
Other elements form oxide
How do alkali metals react with oxygen?
Oxide: Lithium
Peroxide: Sodium
Superoxide: Potassium, Rubidium, Cesium
BUT K AND Rb CAN FORM ALL THREE IF THEY WANT TO
What is KO2 used for?
It is used in submarines for absorbing CO2 and to produce O2
Oxides of alkali metals reaction
Na(exc.) + air → Na2O
Solvay Process
Production of sodium carbonate with the help of NH3, CO2, and NaCl
Potassium carbonate cannot be formed from this process.
Lablanc’s Method
K2CO3 can be prepared from this process using NaCl, H2SO4, and C as a reducing agent
Heating effects on carbonates
All carbonates except for Na, K, Rb, Cs decomposes on heating giving CO2
Alkaline Earth Metals
Beryllium, Magnesium, Calcium, Strontium, Barium, Radium
Atomic Radius Comparison of Alkaline Earth Metals
Be<Mg<Ca<Sr<Ba<Ra
Ionic Radius Comparison of Alkaline Earth Metals
Be+2<Mg+2<Ca+2<Sr+2<Ba+2<Ra+2
Ionisation Energy of Alkaline Earth Metals
Be>Ca>Sr>Ba>Mg
Melting Point of Alkaline Earth Metals
Be>Ca>Sr>Ba>Mg
The distance between the two layers is larger in the lattice of magnesium. Hence melting point of magnesium is the lowest.
Density of alkaline earth metals
Ca<Mg<Be<Sr<Ba
Flame colouration of alkaline earth metals
Ca: Brick Red
Sr: Crimson Red
Ba: Apple Green
Be and Mg do not show any colour
Reaction of alkaline earth metals with air
M + air → MO + M3N2
Be + air → BURNING
Mg + air → FLASH
Comparison of solubility in water for alkaline earth metals
Be>Mg>Ca>Sr>Ba
Formation of lime water
CaO(quick lime) + H2O → Ca(OH)2(slaked lime) + H2O→ Ca(OH)2(s)(milk of lime) + H2O → Ca(OH)2 (lime water)(l)
Uses of Lithium
Preparing parts of the aircraft, armour, electrochemical cells
Uses of Sodium
Making sodium alloys and collant in fast nuclear reaction
Uses of potassium
For fertiliser, soaps, and excellent absorber of CO2 in submarine
Uses in beryllium
For the formation of alloys, and used in making windows of X-ray tables
Uses of magnesium
Used in making alloys, milk of magnesia and toothpaste
Uses of calcium
Extraction of metals from oxide which are difficult to reduce by carbon
Uses of CaO
Manufacturing of cement
Used in the purification of sugar
Uses of Ca(OH)2
Manufacturing of mortar
Whitewashing
Manufacturing of glass and bleaching powder
Uses of CaCO3
Used as marble
Extraction of metals
Antacid