S-block Elements Flashcards
Alkali Metals or Group-1 Metals
Lithium
Sodium
Potassium
Rubidium
Cesium
General electronic configuration of alkali metals
[ns]1
Atomic Radius Comparison of Alkali Metals
Li<Na<K<Rb<Cs<Fr
Difference in radius b/w element: Na-Li>Rb-K>Fr-Cs
Ionisation Energy Comparison of Alkali Metals
Li>Na>K>Rb>Cs>Fr
Ionic Radius Comparison of alkali metals
Li+<Na+<K+<Rb+<Cs+<Fr+
Melting and Boiling Point Comparison of Alkali Metals
It depends upon metallic bond strength.
Li>Na>K>Rb>Cs>Fr
Density Comparison of Alkali Metals
Li<Na<K<Rb<Cs<Fr
Flame colouration of alkali metals
Li: Carmine Red
Na: Golden Yellow
K: Lilac
Rb: Violet
Cs: Blue
How do alkali metals react with moist and dry air?
Lithium forms nitride and oxide
Other elements form oxide
How do alkali metals react with oxygen?
Oxide: Lithium
Peroxide: Sodium
Superoxide: Potassium, Rubidium, Cesium
BUT K AND Rb CAN FORM ALL THREE IF THEY WANT TO
What is KO2 used for?
It is used in submarines for absorbing CO2 and to produce O2
Oxides of alkali metals reaction
Na(exc.) + air → Na2O
Solvay Process
Production of sodium carbonate with the help of NH3, CO2, and NaCl
Potassium carbonate cannot be formed from this process.
Lablanc’s Method
K2CO3 can be prepared from this process using NaCl, H2SO4, and C as a reducing agent
Heating effects on carbonates
All carbonates except for Na, K, Rb, Cs decomposes on heating giving CO2