Hydrogen and its Compounds Flashcards
Hydrogen has similar properties to which groups of the periodic table
Alkali metals - Electronic Configuration
Halogens - Non-metal and existence in diatomic state
Occurrence of hydrogen in nature
Isotropic form = H1, H2, H3
Diatomic Form = Dihydrogen
Lane’s Process
When steam is passed over iron for the production of hydrogen
Fe + H2O(steam)→Fe3O4 + H2
Bosch’s Process
C+H2O→CO + H2O
When Coke and steam react with CO+H2O, then hydrogen is formed.
Hydrogen formation when natural gas is used
Ch4+O2 → CO + H2
When CU2Cl2 and Ni react, then hydrogen is formed.
Two types of dihydrogen
Ortho: whose dipole spin =0
Para: whose dipole sign is not equal to 0
Ortho is more relatively stable than para hydrogen
Industrial method of preparing H2O2
- From 2-ethyl anthraquonone
- By electrolysis
Tests for H2O2
- Rxn with K2Cr2O7
K2Cr2O7 + H2O2 + H2SO4→K2SO4 + CrO5(BLUE) + H2O→Cr2(SO4)3 + H2O - Starch Iodide Paper Test
H2O2+I2→I3- - Rxn with Ti(SO4)2
Ti(SO4)2 + H2O2→H2TiO4+H2SO4
Uses of H2O2
- Used to restore colours of old paintings
- Used as a disinfectant because it reacts with bacteria and converts them
Soap molecules are made up of
Sodium or potassium salts of higher fatty acids
Hard waters are formed by
Bicarbonates, sulphates and chlorides of Calcium and Magnesium
Soft waters forms what with soap
Lather
Ways to remove temporary hardness
Physical Processes - Boiling
Chemical Processes - Clark’s Process
Ways to remove permanent hardness
Physical - No process can remove permanent hardness
Chemical - 1. Soda’s Process/Washing Soda: Calcium reacting with sodium bicarbonates
2. Zeolite Process: Reacting with Sodium Zeolite(Na2Z)
3. Resin Method
4. Calgon’s Method: Reacting with Sodium HexaMeta Phosphate
Different types of hydride
- Ionic Hydrides/Salt-like hydrides: Crystalline and colourless compounds
- Covalent Hydrides/Non-metallic: Elements of p-block except noble gases
- Metallic Hydrides: Elements of d-block