IUPAC Nomenclature Flashcards
Hydrocarbon
Compounds that have at least one carbon and one hydrogen
What are the two types of hydrocarbon?
Saturated Bonds - Alkanes (CnH2n+2)
Unsaturated Bonds- Alkenes(CnH2n) and Alkynes(CnH2n-2)
One carbon, two carbon, three carbon, four carbon, .. How to name them?
Meth, Eth, Prop, But, Pent, Hex, Hept, Oct, Non, Dec
CH4, CH3-CH3
Methane, Ethane
CH2=CH2, CH3-CH=CH2
Ethene, Propene
CH3-CH=CH-CH3
But-2-ene
CH3-CH2-C≡CH
But-1-yne
CH≡CH, CH3-C≡CH
Ethyne, Propyne
Primary Carbon
A carbon atom which is directly attached with only one carbon
Secondary Carbon
A carbon atom which is directly attached with two carbon atoms
Tertiary Carbon
A carbon atom which is directly attached with three carbon atoms
Quarternary Carbon
A carbon atoms which is directly attached with four carbon atoms
Name of F, Cl, Br, I, NO2, NO, NH2
Flouro, Chloro, Bromo, Iodo, Nitro, Nitroso, Amino
Ch4 - H
Methyl(CH3)
Free valent carbon
Carbon that attaches principal carbon chain is called free valent carbon.
n-Alkanes, Iso-alkane, Neo-alkane
Hydrocarbon arranged in a straight chain without branching
If hydrocarbon has n-no. of carbon atoms, then attach (n-1) carbon chain in a straight line and the remaining carbon atom with the second carbon from the left.
If a hydrocarbon contains n-no. of carbon atoms, then (n-2) in a straight chain and the remaining two carbon atoms with 2nd carbon from the left.
What is the priority order of substituent, double or triple bond and functional groups?
Functional Group> Double or Triple Bond> Substituent
Secondary suffix and secondary prefix of alcohol(OH)
ol and Hydroxy
Secondary suffix, secondary prefix and special suffix of carboxylic acid(COOH)
oic, carboxy and carboxylic acid
What is the use of special suffix?
When in a parent carbon chain contains more than two carboxyl group and when carboxyl group attached with a cyclic ring
Secondary suffix, secondary prefix and special suffix of esters(RCOOR)
oate, Alkoxy carbonyl and carboxylate
Secondary suffix, secondary prefix and special suffix of aldehyde(CHO)
al, oxo or formy, carbaldehyde
HCOH, CH3COH
Methanol, Ethanol
Secondary suffix, secondary prefix and special suffix of ketone(RCOR’)
one, keto or oxo and no special suffix
CH3COCH3
Propanone
Secondary suffix, secondary prefix of amines(NH2)
Amine, Amino
CH3-NH-CH3
N-Methyl Methane Amine
CH3-NH-CH2-CH3
N-methyl Ethane Amine
Secondary suffix, secondary prefix and special suffix of amides(RCONH2)
Amide, Carboxamido, Carboxamide
Secondary Prefix of Ethers(OR)
Alkoxy
CH3-O-CH3
Methoxy Methane
CH3-O-CH2-CH3
Ethoxy Ethane
Epoxy(-O-)
Cyclic Esters
Secondary suffix, secondary prefix and special suffix of cyanide(-CN)
NItrile, Cyano and carbonitrile
CH3-CN
Ethane Nitrile